Synthesis, Structure, and Reactivities of Germylborates

甲硼酸盐的合成、结构和反应性

• 批准号: 13640542
• 负责人: MOCHIDA Kunio
• 金额: $ 0.45万
• 依托单位: Gakushuin University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 2001
• 资助国家: 日本
• 起止时间: 2001 至 2002
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-13640542/
• 关键词: Germylborate; Ate complex; X-ray diffraction analysis; Catalytic reaction; X-線構造解析; ゲルマニウム; ホウ素; X線結晶構造; 水溶性; 反応特異性

The structure and reactivity of lithium(germyl)triphenylborates, prepared from unsolvated germyllithium and triphenylboran, with organic substrates in methanol were investigated. The germylborates reacted with acetylenes, organic halides, and acyl halides to give the corresponding germyl-substituted compounds. From the reaction with carbonyl compounds, esters, carboxylic acids, and alkenes, germylborates were completely recovered.

研究了由未溶剂化的锗基锂和三苯基硼烷合成的锗基三苯基硼酸锂的结构及其在甲醇中与有机底物的反应性。甲锗基硼酸酯与乙炔、有机卤化物和酰卤反应，得到相应的甲锗基取代化合物。从与羰基化合物、酯、羧酸和烯烃的反应中，锗基硼酸酯被完全回收。

项目成果

Masato Nanjo, Kazuhiko Matsudo, and Kunio Mochida: "Reactivities of Triethylgermylborate in Methanol"Chem.Lett.. 2001. 1086-1087

Masato Nanjo、Kazuhiko Matsudo 和 Kunio Mochida：“三乙基甲硼酸在甲醇中的反应性”Chem.Lett.. 2001. 1086-1087

Masato Nanjo, Kazuhiko Matsuo, and Kunio Mochida: "Polymeric and Dimeric Structures of Lithium (triethykgermyl)(triphenyl)borate : Synthesis and Characterization"Inorg.Chem.Commun.. in press. (2003)

Masato Nanjo、Kazuhiko Matsuo 和 Kunio Mochida：“锂（三乙基甲锗烷基）（三苯基）硼酸锂的聚合和二聚结构：合成和表征”Inorg.Chem.Commun.. 正在出版。

南条真佐人: "Reactivities of Friethylgermylborate in Methanol"Chem. Lett.. 1086-1087 (2001)

Masato Nanjo：“三乙基甲硼酸在甲醇中的反应性”Chem. 1086-1087 (2001)

Masato Nanjo: "Polymeric and Dimeric Structures of Lithium(Triethylgermyl)(triphenyl)borate : Synthesis and Characterization"Inorg. Chem. Commun.,. (2003)

Masato Nanjo：“（三乙基甲锗烷基）（三苯基）硼酸锂的聚合和二聚结构：合成和表征”Inorg。

Masato Nanjo: "Reactivities of Triethylgermyl borate in Methanol"Chem. Lett.,. 1086-1087 (2001)

Masato Nanjo：“三乙基甲锗烷基硼酸酯在甲醇中的反应性”Chem。