Pational Control of Dimensional Structures of Metal-Assembled Ccmplexes

对金属组装配合物尺寸结构的合理控制进行了研究。这些配合物由银、钯、铂、铜、钴、铁、金、钌和镍等金属与卤素、二乙烯、芘、氰基、环戊二烯和胺等配体结合而成。制备的金属配合物具有三维、二维和一维控制结构，并对其化学物理性质和化学物理功能进行了研究。为了制备这些金属配合物，合成了新的配体。导电，0

We have carried out research for rational control of dimensional structures of metal-assembled complexes. The complexes were prepared with combination between metals such as silver, palladium, platinum, copper, cobalt, iron, gold, ruthenium and nickel and ligands such as halogen, bisthienylethenes, pyrenes, cyano group, cyclopentadienyls and amines. The prepared metal complexes had 3-, 2-, and one-dimensionally controlled structures, and their chemical and physical properties and their chemical and physical functions were studied. In order to prepare these metal complexes, new ligands were synthesized.Electrically conducting, o