Pational Control of Dimensional Structures of Metal-Assembled Ccmplexes

金属组装复合体尺寸结构的局部控制

• 批准号: 10149104
• 负责人: YAMAMOTO Takakazu
• 金额: $ 55.49万
• 依托单位: Tokyo Institute of Technology
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research on Priority Areas (A)
• 财政年份: 1998
• 资助国家: 日本
• 起止时间: 1998 至 2001
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-10149104/
• 关键词: Metal-assembled complex; Dimensional structure; Conductivity; Optical properties; Magnetism; Transition metal complex; Electrochemical response; Polymer-metal complex; 一次元構造; 銀錯体; 10族遷移金属錯体; パイ共役錯体; 電子・光機能; ニッケル錯体; パラジウム錯体; 光機能; ポリポルフィリン /

We have carried out research for rational control of dimensional structures of metal-assembled complexes. The complexes were prepared with combination between metals such as silver, palladium, platinum, copper, cobalt, iron, gold, ruthenium and nickel and ligands such as halogen, bisthienylethenes, pyrenes, cyano group, cyclopentadienyls and amines. The prepared metal complexes had 3-, 2-, and one-dimensionally controlled structures, and their chemical and physical properties and their chemical and physical functions were studied. In order to prepare these metal complexes, new ligands were synthesized.Electrically conducting, o

我们进行了合理控制金属组装配合物的空间结构的研究。这些配合物是由金属如银、钯、铂、铜、钴、铁、金、钌和镍与配体如卤素、双噻吩基乙烯、芘、氰基、环戊二烯基和胺之间的结合制备的。所制备的金属配合物具有三维、二维和一维可控结构，并研究了它们的化学和物理性质以及它们的化学和物理功能。为了制备这些金属配合物，合成了新的配体。

项目成果

M.Yamashita, S.Miya, T.Tanabe: "Charge Fluctuation in MMX Chain Compounds, P_4[Pt_2(pop)_4].nH_2O"J. Am. Chem. Soc.. 121. 2321-2322 (1999)

M.Yamashita、S.Miya、T.Tanabe：“MMX 链化合物中的电荷波动，P_4[Pt_2(pop)_4].nH_2O”J。

T.Yamamoto, K.Shiraishi, M.Abla, I.Yamaguchi, L.B.Groenendaal: "Neutral Poly(3,4-ethylenedioxythiophene-2,5-diyl)s : Preparation by Organometallic Polycondensation and Their Unique d-doping Behavior"Polymer. 43. 711-719 (2001)

T.Yamamoto、K.Shiraishi、M.Abla、I.Yamaguchi、L.B.Groenendaal：“中性聚(3,4-乙烯二氧噻吩-2,5-二基)：有机金属缩聚制备及其独特的 d 掺杂行为”聚合物

T. Yamamoto, K. Shiraishi, M. Abla, I. Yamaguchi, L. B. Groenendaal: "Neutral Poly(3,4-ethylenedioxythiophen-2,5-diyl)s : Preparation by Organometallic Polycondensation and Their Unique d-doping Behavior"Polymer. 43. 711-719 (2001)

T. Yamamoto、K. Shiraishi、M. Abla、I. Yamaguchi、L. B. Groenendaal：“中性聚（3,4-乙烯二氧基噻吩-2,5-二基）：通过有机金属缩聚制备及其独特的 d 掺杂行为”聚合物

T.Yamamoto, K.Shiraishi, M.Abla, I.Yamaguchi, L.B.Groenendaal: "Neutral Poly (3,4-ethylenedioxythiophene-2,5-diyl)s : Preparation by Organometallic Polycondensation and Their Unique p-doping Behavior"Polymer. 43. 711-719 (2001)

T.Yamamoto、K.Shiraishi、M.Abla、I.Yamaguchi、L.B.Groenendaal：“中性聚（3,4-乙烯二氧噻吩-2,5-二基）：有机金属缩聚制备及其独特的 p 掺杂行为”聚合物

K.Marumoto, H.Tanaka, S.Kozaki, S.Kuroda, S.Miya, T.Kawashima, M.Yamashita: "ESR Observation of Average-Valence and Charge-Density-Wave States in Quasi-One-Dimensional Halogen-Bridged Binuclear Metal Complexes"Solid State Commun.. 120. 101 (2001)

K.Marumoto、H.Tanaka、S.Kozaki、S.Kuroda、S.Miya、T.Kawashima、M.Yamashita：“准一维卤素中平均价态和电荷密度波态的 ESR 观察-