Creation of Novel Silicon/Carbon Hybrid Materials based on Fullerene as a Key Molecule

以富勒烯为关键分子创建新型硅/碳杂化材料

• 批准号: 12304038
• 负责人: AKASAKA Takeshi
• 金额: $ 28.17万
• 依托单位: University of Tsukuba (2001-2002)Niigata University (2000)
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (A)
• 财政年份: 2000
• 资助国家: 日本
• 起止时间: 2000 至 2002
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-12304038/
• 关键词: Polsilane; Fullerene; Endohedral metallofullerenes; スーパーアトム; La@C_<82>; アニオン種; 熱的ケイ素化; 酸化還元電位; レドックス物質; 有機ケイ素化号物; 有機ゲルマニウム化合物

Derivatization of fullerenes and endohedral metallofullerenes by the addition of silicon compounds has been developed. It is expected that these silicon derivatives will constitute an important stepping stone on the way to the material, catalytic, and biological applications. The chemical derivatization of endohedral metallofullerenes is especially interesting, since it could lead to new physical and chemical properties which the fullerene derivatives do not have, and provides a new stage in the chemistry of the endohedral metallofullerenes.

在硅化合物的加入下，富勒烯和内生金属富勒烯发生了衍生化反应。预计这些硅衍生物将成为材料、催化和生物应用的重要垫脚石。内嵌金属富勒烯的化学衍生化具有富勒烯衍生物所不具备的新的物理和化学性质，为内嵌金属富勒烯的化学研究提供了一个新的阶段。

项目成果

T. Akasaka: "Silylfullerenes"J. Synth. Org. Chem., Jpn.,. 53. 1066-1076 (2000)

T. Akasaka：“硅基富勒烯”J.

Y. Maeda: "Metal-free Bis-Germylation : C60 -Sensitized Reaction of Digermirane with Benzonitrile"ITE Letters,. 1. 408-411 (2000)

Y. Maeda：“无金属双甲酰化：Digermirane 与苯甲腈的 C60 敏化反应”ITE Letters，。

Y.Takaguchi, T.Tajima, K.Ohta, J.Motoyoshiya, H.Aoyama T.Wakahara, T.Akasaka, M.Fujitsuka and O.Ito: "Reversible C60 Binding to Anthracene Having Dendritic Poly(amide amine) Substituent Producing an Acidic Water-soluble Fullerodendrimer"Angew. Chem. Int.

Y.Takaguchi、T.Tajima、K.Ohta、J.Motoyoshiya、H.Aoyama T.Wakahara、T.Akasaka、M.Fujitsuka 和 O.Ito：“可逆 C60 与具有树枝状聚（酰胺胺）取代基的蒽结合，产生

T.Wakahara, S.Ohkubo, M.Kondo, Y.Maeda, T.Akasaka, M.Waelchli, M.Kako, K.Kobayashi, S.Nagase, T.Kato, K.Yamamoto, X.Gao, E.V.Caemelbecke, and K.M.Kadish: "Ionization and Structural Determination of the Major Isomer of Pr@C82"Chem. Phys. Lett.. 360. 235-23

T.Wakahara、S.Ohkubo、M.Kondo、Y.Maeda、T.Akasaka、M.Waelchli、M.Kako、K.Kobayashi、S.Nagase、T.Kato、K.Yamamoto、X.Gao、E.V.Caemelbecke

Y.Maeda: "C60-sensitized bis-silylation of nitrile and carbonyl compounds with disilirane"J.Organomet.Chem. 611. 414-419 (2000)

Y.Maeda：“C60 敏化的腈和羰基化合物与二硅烷的双甲硅烷基化”J.Organomet.Chem。