Industrialization of direct adhesion between rubbers and polymer-plated metals being excellent in probability and environmental preservation

橡胶与聚合物镀层金属直接粘合的工业化，概率和环境保护优异

• 批准号: 12355027
• 负责人: MORI Kunio
• 金额: $ 27.49万
• 依托单位: Iwate University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (A)
• 财政年份: 2000
• 资助国家: 日本
• 起止时间: 2000 至 2002
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-12355027/
• 关键词: Triazine thiols; Direct Adhesion; Polymer plating; Rubbers; Metals; Interfacial bonds; Crosslinking Agents; None-additives; triazine dithiols; Polymer platings; Direct adhesion; aluminum; Stainless steel; Magnesium alloy; Cast iron; Stain l

The purpose of this sutdy is to develop direct adhesion during curing between rubbers and polymer-plated metals being excellent in probability and environmental preservation and not being influenced curing systems and needing brass and zinc plating. Both peroxide and sulfur curing systems enabled the direct adhesion between acrylic rubber and metals polymer-plated with 6-diallylamino-1, 3, 5-triazine-2, 4-dithiol monosodium indicating next results. For direct adhesion, it is important that the polymer films of three order dimensional structure is formed on metals. Peel strength is influenced by film thickness and polymer plating conditions. Three components among curing agents, softening agents and carbon black show strong interaction for adhesion strength in the direct adhesion of rubbers with polymer-plated metals. The adherends indicated excellent heat, oil and water resistances. The structure of polymer films to obtain high adhesion strength in the direct adhesion of rubbers to metals was found to be that chemical bonds and present at the interface between polymer films and metals, between polymer films and rubbers, and polymer films have high strength.

本研究的目的是在硫化过程中发展橡胶与电镀聚合物金属之间的直接粘合，具有良好的概率和环保性能，不受硫化体系的影响，不需要镀铜和镀锌。过氧化氢和硫磺硫化系统均可使丙烯酸酯橡胶与聚合镀有6-二烯丙氨基-1，3，5-三嗪-2，4-二硫醇单钠的金属直接粘合，预示着下一步的成果。对于直接粘接，重要的是在金属表面形成具有三维结构的聚合物薄膜。剥离强度受薄膜厚度和聚合物镀膜条件的影响。在橡胶与镀聚合物金属的直接粘接中，硫化剂、柔软剂和炭黑中的三种组分对粘接强度表现出很强的交互作用。粘合剂具有优异的耐热、耐油、耐水性能。在橡胶与金属的直接粘接中，获得高粘合强度的聚合物膜的结构是存在于聚合物膜与金属之间、聚合物膜与橡胶之间的界面上的化学键，并且聚合物膜具有高强度。

项目成果

Kunio Mori, J. Oravec, S. Chida: "Magnetically treated conductivenfioms"J. of Materials Sci. Letters. 20. 1187-1188 (2001)

Kunio Mori、J. Oravec、S. Chida：“磁处理导电材料”J。

Y.Oishi, N.Kikuchi, K.Mori, S.Ando, K.Maeda: "Synthesis of Alicyclic Polyimides from Fluorinated Alicyclic Diamine"Journal of Photopolymer Science and Technology. Vol.15, No.2. 213-214 (2002)

Y.Oishi、N.Kikuchi、K.Mori、S.Ando、K.Maeda：“从氟化脂环族二胺合成脂环族聚酰亚胺”光聚合物科学与技术杂志。

ゴンペン, 森邦夫, 大石好行, 穂高武: "有機めっき処理スチールと過酸化物架橋系EPDMとの直接接着"日本ゴム協会誌76巻5号154-159(2003). 76巻5号. 154-159 (2003)

Gompen、Kunio Mori、Yoshiyuki Oishi、Takeshi Hotaka：“有机镀层钢与过氧化物交联 EPDM 之间的直接粘合”日本橡胶协会杂志第 76 卷，第 5 期，154-159（2003 年）第 76 期。 . 5. 154 -159 (2003)

ゴンペン, 森邦夫, 大石好行: "有機メッキ処理金属とアクリルゴムとの直接加硫接着性に及ぼす有機メッキ被膜構造の影響"日本ゴム協会誌. 74(12). 483-489 (2001)

Gompen、Kunio Mori、Yoshiyuki Oishi：“有机镀膜结构对有机镀金属和丙烯酸橡胶之间的直接硫化粘合的影响”日本橡胶协会杂志 74(12) 483-489 (2001)。

史暁東, 森邦夫, 大石好行, 吉田敦: "Mg合金とゴムの加硫接着に及ぼすゴム配合因子の影響"日本ゴム協会誌,210-215,2002年. 75(5). 210-215 (2002)

Gyoto Fumi，Kunio Mori，Yoshiyuki Oishi，Atsushi Yoshida：“橡胶配合因素对镁合金与橡胶之间硫化粘合力的影响”日本橡胶协会学报，210-215，2002。75（5）（2002）。