Spin Dynamics and Quantum Effect in Geometrically Frustrated System

The magnetic properties of molecular clusters attract considerable interest for the new physics involved and for the potential applications.At low temperatures，these molecules act as individual quantum nanomagnets，enabling to probe，at the macroscopic scale，the crossover between quantum and classical physics.Of fundamental interest is the situation of degeneracy of two magnetic levels，where quantum mechanical phenomena such as tunneling or coherence can occur.The situation of degeneracy between levels raises fundamental problems of quantum dynamics.A crucial issue is the role played by the coupling between magnetic molecular levels and the environment such as phonons.The purpose of this project is to verify experimentally the characteristic quantum energy levels and discuss the possible interplay between the anomalous magnetic relaxation phenomena and the level-crossings.for this purpose，a variety of model substances were synthesized by group and some of them were kindly supp…More lied by chemists.The representatives are dimers(Binuclear Complexes)such as Cs3Cr2X9with X=C1，Br，Trimers(Trinuclear Complexes)such as A3Cu3(PO4)4with A=Ca，Sr，trimerized chain system 3CuC12·2dx，polynuclear molecular magnets such as Mn12，Fe12，V15，and so on.We applied various complementary techniques，including advanced crystal preparation，nuclear magnetic resonance，electron spin resonance，neutron scattering，muon spin relaxation，high field magnetization as well as susceptibility and specific heat measurements，in sooperation with many other research groups.A high-field magnetization technique was applied to study the field-dependent behaviors of vsearch groups.A high-field magnetization technique was applied to study the field-dependent behaviors of variarch groups.A high-field magnetization technique was and specific heat measurements，Also，in Fe12molecular magnet which forms a finite chain ring consisting of 12Fe3+(S=5/2)ions，we observed five magnetization steps with equal field spacing，arising from energy-level crossings for the discrete quantum states in the finite spin system。In these examples，we discussed the structure of the energy levels and the relaxation phenomena due to quantum spin dynamics in the metastable states around the level-crossing fields.Also，a figh-frequency electron spin resonance(ESR)texhnique was applied for our purpose，in the wide temperature range down to 0.5K，using high frequency sources up to 800 GHz。Examples are for the S=1/2 Heisenberg antifeiTomagnetic chain system Cu benzoate，Cu(C6H5COO)2·3H_2O and for the trimerized chain system 3CuC12·2dx，in which ferromagnetic trimers consisting of three S=1/2spins coupled antiferromagnetically in one dimension.These results partly have been published already.Less：Less

The magnetic properties of molecular clusters attract considerable interest for the new physics involved and for the potential applications. At low temperatures, these molecules act as individual quantum nanomagnets, enabling to probe, at the macroscopic scale, the crossover between quantum and classical physics. Of fundamental interest is the situation of degeneracy of two magnetic levels, where quantum mechanical phenomena such as tunneling or coherence can occur. The situation of degeneracy between levels raises fundamental problems of quantum dynamics. A crucial issue is the role played by the coupling between magnetic molecular levels and the environment such as phonons. The purpose of this project is to verify experimentally the characteristic quantum energy levels and discuss the possible interplay between the anomalous magnetic relaxation phenomena and the level-crossings.For this purpose, a variety of model substances were synthesized by group and some of them were kindly supp … More lied by chemists. The representatives are dimers (binuclear complexes) such as Cs3Cr2X9 with X = C1, Br, Trimers (trinuclear complexes) such as A3Cu3(PO4)4 with A = Ca, Sr, trimerized chain system 3CuC12・2dx, polynuclear molecular magnets such as Mn12, Fe12, V15, and so on. We applied various complementary techniques, including advanced crystal preparation, nuclear magnetic resonance, electron spin resonance, neutron scattering, muon spin relaxation, high field magnetization as well as susceptibility and specific heat measurements, in sooperation with many other research groups.A high-field magnetization technique was applied to study the field-dependent behaviors of various kind of quantum spin systems by spplying high magnetic field up to 54 T at temperature down to 0.1 K. For example, we observed successive phase transitions at three restricted field regions up to 40 T in the S = 2/3 dimerozed system Cs3Cr2C19. Also, in Fe12 molecular magnet which forms a finite chain ring consisting of 12 Fe3+(S = 5/2) ions, we observed five magnetization steps with equal field spacing, arising from energy-level crossings for the discrete quantum states in the finite spin system. In these examples, we discussed the structure of the energy levels and the relaxation phenomena due to quantum spin dynamics in the metastable states around the level-crossing fields.Also, a figh-frequency electron spin resonance (ESR) texhnique was applied for our purpose, in the wide temperature range down to 0.5 K, using high frequency sources up to 800 GHz. Examples are for the S=1/2 Heisenberg antifeiTomagnetic chain system Cu benzoate, Cu(C6H5COO)2・3H_2O and for the trimerized chain system 3CuC12・2dx, in which ferromagnetic trimers consisting of three S = 1/2 spins coupled antiferromagnetically in one dimension.These results partly have been published already. Less