New synthesis and self-organization of new electron donor ligand,hexathiatrinaphthalene

新型电子给体配体六硫代萘的新合成及自组织

• 批准号: 12640547
• 负责人: SUENAGA Yusaku
• 金额: $ 1.86万
• 依托单位: Kinki University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 2000
• 资助国家: 日本
• 起止时间: 2000 至 2001
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-12640547/
• 关键词: silver(1)complex; tetrathia anthracene; tetrathia anthra-p-hydroguinone; octathiabiphenyl; benzylthio ether group; signal crystak structure; chromism; 短結晶X線構造; 結晶構造

Benzopolythia compounds, tribenzo-1, 4, 5, 8, 9, 12 -hexathiatriphenylene (btt), dibenzo-1, 4, 5, 8-tetrathia anthracene (bta), dibanzo-1, 4, 5, 8, -tetrathia-9, 10-hydroxyanthracene (bthg), tetra (1, 4-dithia naphtho) [a, c, f, h] naphthalene (tdnn) and tetrabenzo-2, 2', 3, 3', 5, 5', 6, 6'-octathiabiphenyl (btb) have been synthesized in high yields by the reaction of the thiolate anion of the o-benzenedithiol with the corresponding fluoro-substituted aromatic compounds in the presence of anhydrous K2CO3.X-ray analyses of the molecular structures of btt, bta and bthg show a stable chair-shaped comformation with interplanar angles between the phenyl rings and center benzene ring in the range of 132-143°for btt, 125.4°for bta and 131-136°for bthg The silver (1) complex with btt has been prepared and its molecular structure determined by S-ray crystallography which gives a novel di-nuclear silver (1) complex.

苯并多硫化合物，三苯并-1，4，5，8，9，12 -六硫杂苯并菲（BTT），二苯并-1，4，5，8-四硫杂蒽（BTA），二苯并-1，4，5，8-四硫杂-9，10-羟基蒽（BTHG），（1，4-二硫杂萘并）[a，c，f，h]萘（TDNN）和四苯并-2，2 ′，3，3 ′，5，5 ′，6，通过邻苯二硫醇的硫醇根阴离子与相应的氟代联苯反应，高产率地合成了6 ′-八硫联苯（BTB）。btt、bta和bthg的X射线衍射分析表明，btt具有稳定的椅型构象，苯环与中心苯环的面夹角在132 ° ~ 143°之间，合成了btt与银（1）配合物，用单晶衍射法测定了配合物的分子结构，得到了一种新的双核银（1）配合物。

项目成果

Yusaku Suenaga: "Bezopolythia compounds and di-nuclear silver(I) complex with tribenzo-1, 4, 5, 8, 9, 12-hexathiatriphenylene as new electron donor ligand: synthesis, crystal structure and properties"Science and Technology. 14(14). 25-33 (2002)

Yusaku Suenaga：“Bezopolythia化合物和以三苯并-1,4,5,8,9,12-六硫苯并菲为新电子给体配体的双核银(I)络合物：合成、晶体结构和性质”科学与技术。

Yusaku Suenaga: "Three-dimensional silver(1) co-ordination polymer with pocket structures"J.Chem.Soc., Dolton Transactions. 3620-3623 (2002)

Yusaku Suenaga：“具有口袋结构的三维银（1）配位聚合物”J.Chem.Soc.，Dolton Transactions。

Yusaku Suenaga: "Three-Dimensional Silver (I) Co-ordination Polymer with Pocket Structures"J.Chem Soc., Dalton Transactions. 3620-3623 (2000)

Yusaku Suenaga：“具有口袋结构的三维银 (I) 配位聚合物”J.Chem Soc.，Dalton Transactions。

Yusaku Suenaga: "Structural control of silver(1) co-ordination polymers"Inorg.Chim.Acta. 308. 17-21 (2000)

Yusaku Suenaga：“银（1）配位聚合物的结构控制”Inorg.Chim.Acta。

Yusaktu Suenaga: "Structural Control of Silver (I) Co-ordination Polymers : Construction of Two-and Three-Dimensional Frameworks of Silver (I) ions Bridged by Dicyanopyrazine"Inorg.Chim.Acta. 308. 17-21 (2000)

Yusaktu Suenaga：“银（I）配位聚合物的结构控制：二氰基吡嗪桥联的银（I）离子的二维和三维框架的构建”Inorg.Chim.Acta。