Synthesis, Structure, and Emissive Properties ofPt(II) Complexes with a Hydrazone Ligand

腙配体 Pt(II) 配合物的合成、结构和发射性能

• 批准号: 17550056
• 负责人: NAKAJIMA kiyohiko
• 金额: $ 2.14万
• 依托单位: Aichi University of Education
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 2005
• 资助国家: 日本
• 起止时间: 2005 至 2007
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17550056/
• 关键词: Platinum(II) complex; Hydrazone; Emission; Protonation and deprotonation; Photoreaction; Structure; Synthesis; 分子構造; プロトン濃度; 白金(II)錯体; ヒドラゾン配位子; 構造

We prepared hydrazone ligands derived from 2-hydrazinopyridine, 2-hydrazinoquinoline, benzoylhydrazine, picolinic hydrazide and 2-(alkylthio)benzaldehyde (R = Me, Bu, 4-chlorophenyl)or 2-(diphenylphosphino)benzaldehyde. The NH hydrogen atoms of the coordinated hydrazone ligands on the metal complexes(M = Pd(Il), Pt(11), and Ru(Il)) were easily protonated or deprotonated by the action of acids and bases. The reaction was followed spectrnphotometrically, and the isosbestic points were observed for Pd(II) and Pt(11) complexes. The Ru(II) complexes were oxidized by air after deprotonation to yield Ru complexes. The uncoordinated hydrazone ligands and their Pd(II) and Rua() complexes was not emissive, however, the Pt(11) complexes showed strong emission peaks in the visible region. Reversible large sifts of the emission peaks were observed by the action of acids and bases

我们制备了由2-肼基吡啶、2-肼基喹啉、苯甲酰肼、吡啶甲酰肼和2-(烷硫基)苯甲醛(R = Me、Bu、4-氯苯基)或2-(二苯基膦)苯甲醛衍生的腙配体。金属配合物(M = Pd(II)、Pt(11)和Ru(II))上配位腙配体的NH原子很容易在酸和碱的作用下质子化或去质子化。通过分光光度法跟踪反应，并观察 Pd(II) 和 Pt(11) 配合物的等吸光点。 Ru(II)配合物去质子化后被空气氧化，生成Ru配合物。不配位腙配体及其Pd(II)和Rua()配合物不具有发射性，然而，Pt(11)配合物在可见光区域显示出强发射峰。通过酸和碱的作用观察到发射峰的可逆大筛分

项目成果

Laser Photolysis Studies of the Reaction of Chromium(II)Octaethylporphyrin Complex with Triphenylphosphine and Triphenylphosphine Oxide

八乙基卟啉铬(II)配合物与三苯基膦和三苯基氧化膦反应的激光光解研究

• 发表时间: 2005
• 期刊: Inorg. Chem 44
• 作者: M. Inamo;N. Matsubara;K. Nakajima;T. S. Iwayama;H. Okimi;M. Hoshino;Inorg. Chem
• 通讯作者: Inorg. Chem

Activation of C-H and C-C bonds of formyl group on the complexes

配合物上甲酰基C-H和C-C键的活化

• 发表时间: 2007
• 作者: Syogo;Ando;et. al.
• 通讯作者: et. al.

サリチリデンー2-アミノエタノール配位子を用いたキュバン型錯体の合成と電子状態

使用水杨基-2-氨基乙醇配体的古巴型配合物的合成和电子态

• 发表时间: 2007
• 作者: Kazuyuki;Hino;et. al.;日野 和之
• 通讯作者: 日野 和之

Kinetic Studies on the Reversible Ring Opening closure Reaction of the Triazine Liagand and Structural Properties of Palladium(II) Complexes

三嗪配体可逆开环闭环反应的动力学研究及钯(II)配合物的结构性质

• 发表时间: 2007
• 期刊: Inorg.Chim.Acta 360
• 作者: M. Zhang;M. Inamo;M. Kojima;K. Nakajima;M. Zhang
• 通讯作者: M. Zhang

Photoreactivity of the Pt(II) complexes containing hydrazone ligands

含腙配体的 Pt(II) 配合物的光反应性

• 发表时间: 2007
• 作者: Hiroyuki;Horiki;et. al.
• 通讯作者: et. al.