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Studies on selectivity of new functional material with loaded solvent extraction reagents on silica gel

Studies on selectivity of new functional material with loaded solvent extraction reagents on silica gel
硅胶负载溶剂萃取剂新型功能材料选择性研究
批准号:
19550093
负责人:
KOKUSEN Hisao
金额:
$3.0万
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (C)
财政年份:
2007
资助国家:
日本
项目状态:
已结题
起止时间:
2007 至 2009

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中文摘要
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英文摘要
The alkyl chain was introduced to the surface of silica gel. The new separation material which is loaded extraction reagent on the surface of silica gel was synthesized. The selectivity of metal ions was improved compared with the solvent extraction method when the transition metal ion was separated using new separation material. It was considered that the reason of improving selectivity of metal ions was a hole of silica gel. The separation material was synthesized using silicate which had different pore size, and it was researched to the adsorption of metal ions. As a result, it was understood that the relation is not seen in a pore size and the selectivity. The adsorption of Ga and In have been researched as an applied research. As a result, the adsorption mechanisu of Ga and In from aqueous solution was similar to the solvent extraction system.
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DOI: --
发表时间: 2007
期刊:
影响因子: --
作者: [國仙久雄, 久保埜公二, 大嶋俊一, 平山直紀]
通讯作者: 平山直紀
DOI: --
发表时间: 2008
期刊: Proceedings of ISEC 2008 2
影响因子: --
作者: [Syunichi Oshima, Junji Noro, Kaoru Fujinaga, Hisao Kokusen, Shigekazu Tsurubou, Yu Komatsu]
通讯作者: Yu Komatsu
Adsorption Behavior of Divalent Transition Metal Ions with b-diketon Retained on Octadecyl Silica Gel.
十八烷基硅胶上保留的 b-二酮对二价过渡金属离子的吸附行为。
DOI: --
发表时间: 2007
期刊: Journal of Ion Exchange 18(4)
影响因子: --
作者: [Masamitsu Iiyama, Hisao Kokusen, Shigekazu Tsurubou, Y. Komatsu]
通讯作者: Y. Komatsu
Solvent Extraction of Alkaline Earth Metal IonsUsing N, N-Bis(2-hydroxy-5-nitrophenylmethyl)-N, N-bis(2-pyridylmethyl)-1. 2-ethanediamine
使用 N, N-双(2-羟基-5-硝基苯基甲基)-N, N-双(2-吡啶基甲基)-1 溶剂萃取碱土金属离子。
DOI: --
发表时间: 2007
期刊: Journal of Ion Exchange 18(4)
影响因子: --
作者: [Syunichi Oshima, Naoki Hirayama, Koji Kubono, Hisao Kokusen]
通讯作者: Hisao Kokusen
13
    Study of complex formation and selectivity of new bis-beta-diketone type ligand using solvent extraction method
    • 批准号:
      17K05895
    • 项目类别:
      Grant-in-Aid for Scientific Research (C)
    • 资助金额:
      $3.08万
    • 财政年份:
      2017
    • 负责人:
      KOKUSEN Hisao
    • 依托单位:
    The clarification of mechanism of the selectivity and recovery of trivalent cation of new separation materials loaded solvent extraction reagent.
    • 批准号:
      23550091
    • 项目类别:
      Grant-in-Aid for Scientific Research (C)
    • 资助金额:
      $3.41万
    • 财政年份:
      2011
    • 负责人:
      KOKUSEN Hisao
    • 依托单位:
    海外基金