Search for semiochemicals of honeybee (Apis mellifera)

搜索蜜蜂 (Apis mellifera) 的化学信息素

• 批准号: 20510208
• 负责人: NODA Naoki
• 金额: $ 2.41万
• 依托单位: Setsunan University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 2008
• 资助国家: 日本
• 起止时间: 2008 至 2010
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20510208/
• 关键词: 天然有機化学; ミツバチカスト制; 制御物質; semiochemicals; ローヤルゼリー; ヒドロキシ脂肪酸; Johnstonの仮説; 10-hydroxydecenoic acid; ミツバチ; カスト制

This study was undertaken to search for semiochemicals, which have various important functions and roles for caste maintenance in honeybee colonies (Apis mellifera). Rather than looking for semiochemicals in the mandibular glands of the queen bee, this study involves the search for precursors of pheromones from large quantities of royal jelly. Seven chiral hydroxy fatty acids were isolated. Interestingly enough, except for 3-hydroxyl fatty acid, all chiral acids are present in royal jelly as optical isomers. Considering the relationship between 9-ODA and 9-HDA, it is expected that these chiral acids are precursors of semiochemicals, and that their corresponding oxo-forms may play physiologically important functions and roles in the hierarchy of honeybee colonies. The biological activities of these compounds will be examined.

本研究旨在寻找在蜜蜂群体中对维持等级具有各种重要功能和作用的符号化学物质。这项研究不是在蜂王的下颌腺中寻找化学物质，而是从大量的蜂王浆中寻找信息素的前体。分离得到7种手性羟基脂肪酸。有趣的是，除了3-羟基脂肪酸，所有的手性酸都以光学异构体的形式存在于蜂王浆中。考虑到9-ODA和9-HDA之间的关系，我们预计这些手性酸是半化学物质的前体，其相应的氧合形式可能在蜜蜂群体的等级结构中发挥重要的生理功能和作用。我们将对这些化合物的生物活性进行研究。

项目成果

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The Absolute Configurations of Some Hydroxy Fatty Acids from the Royal Jelly of Honeybees (Apis mellifera)

蜜蜂蜂王浆中某些羟基脂肪酸的绝对构型

• 发表时间: 2011
• 期刊: Lipids(AOCS,アメリカ油化学会)
• 作者: 枝村佳奈;他;野田直規
• 通讯作者: 野田直規

The Absolute Configurations of Some Hydroxy Fatty Acids from the Royal Jelly of Honeybees (Apis mellifera).

蜜蜂（Apis mellifera）蜂王浆中某些羟基脂肪酸的绝对构型。

• 发表时间: 2011
• 期刊: Lipids 46
• 作者: Kodai T.;Nakatani T.;Noda N.
• 通讯作者: Noda N.

Absolute Configurations of Some Hydroxy Fatty Acids from the Royal Jelly of Honeybees (Apis mellifera).

蜜蜂（Apis mellifera）蜂王浆中某些羟基脂肪酸的绝对构型。

• 发表时间: 2010
• 作者: 小鯛哲也;中谷尊史;野田直規
• 通讯作者: 野田直規