Magnetic Properties of Porous Metal-Organic Hybrid Crystals Absorbing Molecular Gases

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Porous metal-organic hybrid compounds have been studied for such as gas absorption and catalysis. In addition, their applications as gas sensors have been demonstrated by use of the change in magnetic or optical properties upon gas absorption and desorption. These experiments have been performed ex-situ. It is necessary to understand the properties in-situ, in particular to follow the performance of the materials continuously. Then we have developed an in-situ apparatus and studied the gas sorption effects on the magnetism of porous metal-organic hybrid compounds.