Synthesis of the Group 6 Metal Complexes Related to Hydroxylase Active Sites using Water as a Reactant and Their Catalytic Activities

点击翻译按钮获取中文摘要

Molybdenum(VI)-oxo, -sulfido, and -selenido complexes were prepared. Upon oxidizing oxomolybdenum(IV) complexes electrochemically or chemically in the presence of water, six-coordinate dioxomolybdenum(VI) complexes having one oxo group derived from the water molecule were prepared. Additionally, sulfido-, and selenido-molybdenum(VI) complexes were prepared from its silanolate derivative and the hydrogensulfide or hydrogenselenide. The effects of the terminal sulfido and selenido groups on the atom transfer reactivity and electronic structures were examined.