Development of Electrochemical Determination for Halogenated Organic compounds

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The final purpose of this project is the development of electrochemical determination for halogenated organic compounds, most of which are very toxic. In order to achieve the purpose, we have mainly carried out two types of experiments as follows: 1) Voltammetric behavior of metal complexes with various salen ligands was investigated to elucidate the effect of lithium ion and relationship between ligand type and redox potential. 2) The reaction of electrogenerated metal(I)-salen complexes with halogenated organic compounds was examined with various electrochemical measurements to find out that the light irradiation on the surface of electrode accelerate de-haloganation reaction