Supramolecular Synthetic Chemistry Constructed for Giant and Complicated Functional Systems

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Some supramolecular systems based on porphyrin derivatives have been constructed. Trisporphyrin derivatives gave supramolecular nanoring spontaneously. Supramolecular composites of the nanoring and energy acceptors were produced by complementary metal-ligand coordination. Tube-like supramolecular structures were also constructed from porphrin nanorings having six benzoic acid groups by complementary hydrogen bondings. These results must contribute to artificial photosynthesis and nanochemistry.