Synthesis of hypervalent organoantimony and bismuth compounds and their application for organic synthesis

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Carbon-carbon,-nitrogen, and-oxygen bonds formation by transition metal-catalyzed cross-coupling reaction is one of the most important reaction in organic synthesis and considerable attention has been paid for developing this methodology in the last two decades. In the course of our research program for advance of hypervalent organoantimony and bismuth compounds in organic synthesis, we disclosed that these hypervalent compounds played important roles as both transmetallating agents and pseudo-halides in a wide variety of transition metal-catalyzed cross-coupling reactions.