Synthesis of Strained Macrocyclic Compounds and Their Application to Functionalized Materials

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In this study, tin-mediated reductive aromatization afforded strained π-conjugated cyclynes such as pyridine-containing strained cyclynes and p-phenyleneacetylene derivatives. The former compound emits fluorescence around 500-600 nm with a good quantum yield. The latter compounds can form 1:1 complexes with fullerene derivatives.