Synthesis and Functions of New Polymers with Perfectly Controlled Densities and Distributions of Side Chain Functional Groups

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It has been relatively easy to synthesize polymers with relative densities of side chain functional groups in the conventional polymerization method. In this work, we have utilized isomerization cyclopolymerization of dienes by using palladium complexes with diimine ligands and succeeded in synthesize polymers with various side chain functional groups, whose densities and distributions are controlled perfectly. New isomerization addition polymerization has been discovered and the produced polymer was found to show liquid crystalline properties.