Development of New Molecule-Based and Nano Magnets Containing Acetylide Complexes

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New magnetic materials containing chromium-acetylide complexes were developed. Based on the result, a new chromium acetylide complex was synthesized where TTF-type molecules, which is a typical conductive organic molecule, was employed as ligands. In the oxidation state of the complex, an extraordinary strong exchange interaction is observed between a chromium cation and TTF-type ligands, indicating that the complex is promising to construct strongly interacting π-d systems.