Synthesis of Fluorescent Metal Complexes Possessing Solid-state Photoelectronic Properties and their Applications to Optoelectronic Devices

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We have designed and synthesized novel fluorescent dye ligand (1) and their ruthenium complex (2), and their photophysical and electrochemical properties have been investigated. Furthermore, dye-sensitized solar cells (DSSCs) were fabricated using the fluorescent dye ligand (1) and their metal complex (2). The solar energy-to-electricity conversion yields (η) are 0.2% for fluorescent dye ligand (1) and 0.1% for ruthenium complex (2) respectively.