Synthesis of the Multinuclear Transition Metal Complexes with Mechanically Interlocked Flexible Structures and Its Application
Synthesis of the Multinuclear Transition Metal Complexes with Mechanically Interlocked Flexible Structures and Its Application
批准号:
21750058
负责人:
SUZAKI Yuji
金额:
$2.91万
依托单位国家:
日本
项目类别:
Grant-in-Aid for Young Scientists (B)
财政年份:
2009
资助国家:
日本
项目状态:
已结题
起止时间:
2009 至 2010
中文摘要
合成了含钯(II)的易溶大环化合物。大环化合物的骨架包含18个碳原子和6个氧原子。采用由两个大环分子串成的联锁分子作为双金属催化剂,进行了双官能化底物的1:1环化反应。
英文摘要
The facile macrocyclic compounds bearing palladium(II) were synthesized. The framework of macrocyclic compounds contain 18 carbon atoms and 6 oxygen atoms. The interlocked molecules composed of two macrocyclic molecules threaded by a liner molecule were employed as the bimetallic catalyst for the 1:1 cyclization reaction of difunctionalized substrates.
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会议论文
Development of Organometallic Rotaxanes and the Control of Molecular Motion and Its Photochemical Properties by Redox Reaction of Ferrocene Unit
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批准号:19750044
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项目类别:Grant-in-Aid for Young Scientists (B)
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资助金额:$2.34万
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财政年份:2007
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负责人:SUZAKI Yuji
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依托单位:
海外基金