Development of Novel Transformations via Cleavage of Inactive Bonds using Group 7 Transition Metal Catalysts
Development of Novel Transformations via Cleavage of Inactive Bonds using Group 7 Transition Metal Catalysts
批准号:
21750103
负责人:
KUNINOBU Yoichiro
金额:
$3.0万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Young Scientists (B)
财政年份:
2009
资助国家:
日本
项目状态:
已结题
起止时间:
2009 至 2011
中文摘要
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英文摘要
We focused on group 7 transition metal compounds, such as rhenium and manganese complexes, and carried out investigations to develop novel and efficient transformations using such complexes as catalysts. As a result, we have succeeded in the development of transformations via the cleavage of C-H or C-C bond, which forms skeletons of organic molecules and is difficult to be cleaved. In addition, we also developed regioselective cycloaddition reactions.
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Synthesis of Multisubstituted Cyclopentadienes from Cyclopentenones Prepared via Catalytic Double Aldol Condensation and Nazarov Reaction Sequence.
通过催化双羟醛缩合和纳扎罗夫反应序列从环戊烯酮合成多取代环戊二烯。
DOI:
10.1002/chin.201210047
发表时间:
2011
期刊:
ChemInform
影响因子:
--
作者:
[Y. Nishina, Tomohiro Tatsuzaki, Ayano Tsubakihara, Y. Kuninobu, K. Takai]
通讯作者:
K. Takai
DOI:
10.1016/j.jorganchem.2010.09.064
发表时间:
2011
期刊:
Journal of Organometallic Chemistry
影响因子:
2.3
作者:
[Y. Kuninobu;Takahiro Nakahara;P. Yu;K. Takai]
通讯作者:
Y. Kuninobu;Takahiro Nakahara;P. Yu;K. Takai
DOI:
10.1039/c0cc00243g
发表时间:
2010-07
期刊:
Chemical communications
影响因子:
4.9
作者:
[Y. Kuninobu;Tomonari Ureshino;S. Yamamoto;K. Takai]
通讯作者:
Y. Kuninobu;Tomonari Ureshino;S. Yamamoto;K. Takai
DOI:
10.1002/asia.200900137
发表时间:
2009-01-01
期刊:
CHEMISTRY-AN ASIAN JOURNAL
影响因子:
4.1
作者:
[Kuninobu, Yoichiro, Kawata, Atsushi, Takai, Kazuhiko]
通讯作者:
Takai, Kazuhiko
Cross-Coupling Reactions between C(sp^2)-H and C(sp^3)-H Bonds via Sequential Dehydrogenation and C-H Insertion
C(sp^2)-H 和 C(sp^3)-H 键之间通过顺序脱氢和 C-H 插入的交叉偶联反应
DOI:
--
发表时间:
2010
期刊:
Synlett
影响因子:
2
作者:
[Kuninobu, Y.; Asanoma, D.; Takai, K]
通讯作者:
K
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