Ultrasound-Induced Gelation Directed towards Spatial Arrangement of Metal Complexes

磷光发射的即时和精确的控制可以通过超声诱导的有机液体与环状双核铂配合物与双（水杨醛亚胺）配体的凝胶化来进行。凝胶的发射可以通过超声处理时间、接头长度和复合物的光学活性来控制。一些实验结果表明，结构依赖的同质和异质性聚集体和超声波控制的聚集体形态的发射增强的关键因素。

Instant and precise control of phosphorescent emission can be performed by ultrasound-induced gelation of organic liquids with cyclic dinuclear platinum complexes with bis(salicylaldiminato) ligands. Emission from the gels can be controlled by sonication time, linker length, and optical activity of the complexes. Several experimental results indicated that structure-dependent homo-and heterochiral aggregations and ultrasound-control of the aggregate morphology are key factors for emission enhancement.