Development of the functional composite resins with cyclodextrins

环糊精功能复合树脂的研制

• 批准号: 21791957
• 负责人: MAKITA Yoshimasa
• 金额: $ 1.25万
• 依托单位: Osaka Dental University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Young Scientists (B)
• 财政年份: 2009
• 资助国家: 日本
• 起止时间: 2009 至 2010
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21791957/
• 关键词: シクロデキストリン; コンポジットレジン

The functional composite resins with cyclodextrins have been developed for the relaxation of the stress on the tooth surface due to the polymerization shrinkage behavior in composite resins. According to the results, the formation of pseudorotaxane with the monomer which composed of composite resin and cyclodextrins were demonstrated. The novel molecular capsule which had three entrances and was stable in intraoral condition was synthesized and characterized. The molecular capsule which introduced the metal ion into the cavity was elucidated.

由于复合树脂中的聚合收缩行为，已经开发了具有环糊精的功能复合树脂来松弛牙齿表面上的应力。实验结果表明，复合树脂与环糊精组成的单体能够生成准轮烷。合成并表征了一种具有三个入口且在口腔内条件下稳定的新型分子胶囊。阐明了将金属离子引入空腔的分子囊。

项目成果

Zinc(II)-included hemicryptophane : coordination of an acetonitrile guest within the cavity.

含锌 (II) 的半隐烷：乙腈客体在空腔内的配位。

• 发表时间: 2011
• 期刊: Supramol.Chem. 23
• 作者: Makita;Y.; Sugimoto;K.; Furuyoshi;K.; Ikeda;K.; Fujita;T.; Fujiwara;S.; Ogawa;A.
• 通讯作者: A.

Zinc(II)-included hemicryptophane : coordination of an acetonitrile guest within the cavity

含锌 (II) 的半隐芬烷：乙腈客体在空腔内的配位

• 发表时间: 2011
• 期刊: Supramolecular Chemistry
• 影响因子: 3.3
• 作者: 牧田佳真;杉本和也;古吉健太;池田敬祐;藤田智之;藤原眞一;小川昭弥
• 通讯作者: 小川昭弥

A zinc(II)-included hemicryptophane : facile synthesis, characterization, and catalytic activity.

含锌 (II) 的半加密烷：易于合成、表征和催化活性。

• 发表时间: 2010
• 期刊: Inorg.Chem. 49
• 作者: Makita;Y.; Sugimoto;K.; Furuyoshi;K.; Ikeda;K.; Fujiwara;S.; Shin-ike;T.; Ogawa;A.
• 通讯作者: A.