Construction of Functional Self-Assembled Systems based on DynamicProperty of Metal Ions

本研究以六苯为原料，通过两步反应合成了C3对称六苯衍生物。应用这种方法，C3对称的三单齿配体轴承三个吡啶基的制备，并利用八面体形状的自组装Zn（II）-胶囊配合物的建设。的Zn（II）-胶囊内的空腔，这是被取代的磺酸根配体选择性的阴离子单齿配体，因此，所得的配位胶囊的内部空间很容易与各种官能团的改性。

In this study we developed a novel synthetic method of C3 symmetric hexaphenylbenzene derivatives from hexaphenylbenzene in two steps. Applying this method, a C3 symmetric tris-monodentate ligand bearing three pyridyl groups was prepared, and was utilized for the construction of an octahedron-shaped self-assembled Zn(II)-capsule complex. The Zn(II)-capsule has anionic monodentate ligands inside the cavity, which were replaced with sulfonate ligands selectively, and thus the inner space of the resulting coordination capsule was easily modified with a variety of functional groups.