Dioxygen Activation on Transition Metal Centers Tuned by Mimicking Non-heme Iron Active Sites

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We succeeded in synthesizing a substrate-binding dicopper μ-η^2:η^2-peroxo complex and characterizing it spectroscopically. We also found that substrate binding to the copper center could accelerate formation of the active dioxygen intermediate species. In the manganese and iron complex systems, we obtained several findings involving the corresponding high-covalent metal oxo species.