Three-dimensional and functional interface designs by bottom-up composite processing using fine-nanosized particles

使用细纳米粒子通过自下而上复合加工进行三维和功能界面设计

• 批准号: 23360323
• 负责人: ABE Hiroya
• 金额: $ 10.07万
• 依托单位: Osaka University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (B)
• 财政年份: 2011
• 资助国家: 日本
• 起止时间: 2011-04-01 至 2014-03-31
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23360323/
• 关键词: ナノ粒子; 複合化; 三相界面; アセンブリ; 多孔体

A composite bottom-up processing has been investigated for syntheses of nanocomposite particles, based on utilization of dispersion and coagulation of fine-nanosized oxide particles (<10nm). Anode and cathode electrode materials of solid oxide fuel cells (SOFC), has been synthesized by the newly developed method. It was also demonstrated that the performances of electrodes fabricated from these nanocomposite particles are enhanced due to formation of large triple phase boundary. A multiple co-precipitation method has been studied using anionic Zr carbonate complex, and it has been demonstrated that homogenous nanocomposite particles are synthesized by this method. An anode-supported SOFC with a nanostructured Ni-YSZ anode active layer was fabricated using the nanocomposite particles, and a relatively high power density wad observed.

利用氧化物细纳米颗粒（<10 nm）的分散和凝聚作用，研究了一种自下而上的复合工艺制备纳米复合颗粒。用这种新方法合成了固体氧化物燃料电池（SOFC）的正负极电极材料。研究还表明，由于形成了大的三相界面，由这些纳米复合颗粒制成的电极的性能得到了增强。研究了一种使用阴离子碳酸锆络合物的多重共沉淀方法，并证明了通过该方法合成了均匀的纳米复合颗粒。利用该纳米复合粒子制备了具有纳米结构Ni-YSZ阳极活性层的阳极支撑SOFC，并观察到了较高的功率密度。

项目成果

Colloidal dispersibility of fatty acid-capped iron nanoparticles and its effect on static and dynamic magnetorheological response

脂肪酸封端铁纳米颗粒的胶体分散性及其对静态和动态磁流变响应的影响

• DOI: 10.1016/j.colsurfa.2012.10.012
• 发表时间: 2012
• 期刊: Colloids Surf. A
• 作者: Shinya Yamanaka; Yoshikazu Kuga et. al.
• 通讯作者: Yoshikazu Kuga et. al.

ビルドアップ粒子複合化と SOFC 電極開発

堆积颗粒复合材料和SOFC电极开发

• 发表时间: 2013
• 作者: Manirakiza;Eric; Seto;Takafumi; Osone;Saho; Fukumori;Kanta; Otani;Yoshio;H. Inoue;Takafumi Seto;Yuichi Setsuhara;阿部浩也,近藤 光,内藤牧男
• 通讯作者: 阿部浩也,近藤 光,内藤牧男

Novel Co-precipitation method to synthesize NiO–YSZ nanocomposite powder for solid oxide fuel cell

• DOI: 10.1016/j.apt.2013.08.001
• 发表时间: 2014-03
• 期刊: Advanced Powder Technology
• 影响因子: 5.2
• 作者: Xiuan Xi;H. Abe;K. Kuruma;R. Harada;Anze Shui;M. Naito

炭酸Zr錯体溶液を用いる新規共沈法とSOFC電極用複合ナノ粒子の合成

碳酸盐锆络合物溶液共沉淀新方法及SOFC电极用复合纳米颗粒的合成

• 作者: 奚 修安;阿部浩也;來間和男;近藤光;内藤 牧男
• 通讯作者: 内藤 牧男

Build-up route to synthesize nanocomposites for enlarging TPB in SOFC anode electrodes

合成用于扩大 SOFC 阳极电极中 TPB 的纳米复合材料的构建路线

• 发表时间: 2013
• 作者: H. Abe;X. Xi;A. Kondo;M. Naito
• 通讯作者: M. Naito