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Elucidation and application of the multifunctional expression mechanism of the environment-oriented optical active hybrid complex

Elucidation and application of the multifunctional expression mechanism of the environment-oriented optical active hybrid complex
面向环境的光学活性杂化复合物多功能表达机制的阐明及应用
批准号:
23550181
负责人:
YONEMURA TOSHIAKI
金额:
$3.24万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (C)
财政年份:
2011
资助国家:
日本
项目状态:
已结题
起止时间:
2011 至 2013

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中文摘要
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英文摘要
We found a specific method to prepare the optical active polynuclear complexes stereoselectively, and on the other hand, it could obtain a various formation ratio by the use of other complexes. Furthermore, it is clarified that we could easily change the polynuclear structures when we changed the substituent of the ligands. We were able to get the knowledge concerning the additional factor for the chiral selectivity in the environmental response type complexes. Since there were remarkable differences between the stereospecificity and the solubility in those products, it is thought that the value as the useful materials are risen. These study contents, which aim at the development of the environmental response type optical active polynuclear complexes, continually examine after a grant period, and we want to enlarge the functional expression using this system.
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DOI: 10.1039/c3cc46544f
发表时间: 2013-11
期刊: Chemical communications
影响因子: 4.9
作者: [Haiyan Ma;Kohei Matsuzaki;Yudong Yang;Etsuko Tokunaga;Daisuke Nakane;T. Ozawa;H. Masuda;N. Shibata]
通讯作者: Haiyan Ma;Kohei Matsuzaki;Yudong Yang;Etsuko Tokunaga;Daisuke Nakane;T. Ozawa;H. Masuda;N. Shibata
2-ピリミジンチオレートを用いたコバルト-銀混合錯体の合成と反応性
2-嘧啶硫醇盐钴银混合配合物的合成及其反应活性
DOI: --
发表时间:
期刊:
影响因子: --
作者: [上森隆裕, 米村俊昭]
通讯作者: 米村俊昭
異性体を有するモノチオラトコバルト錯体と銀イオンとの集積化反応
单硫醇钴配合物与异构体和银离子的整合反应
DOI: --
发表时间: 2012
期刊:
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作者: [Chitoshi Kitamura, Akira Takenaka, Takeshi Kawase, Takashi Kobayashi, Hiroyoshi Naito, 岡﨑麻紗,森田昌光,松本健司,小澤智宏,米村俊昭]
通讯作者: 岡﨑麻紗,森田昌光,松本健司,小澤智宏,米村俊昭
DOI: --
发表时间: 2011
期刊:
影响因子: --
作者: [北村千寿, 監修:赤阪健, 大須賀篤弘, 福住俊一, 神取秀樹, 小野大助, T.Yonemura and T.Ozawa]
通讯作者: T.Yonemura and T.Ozawa
34
    Elucidation and application of environmental response function expression mechanism using chiral growth type aggregation reaction
    • 批准号:
      15K05587
    • 项目类别:
      Grant-in-Aid for Scientific Research (C)
    • 资助金额:
      $3.08万
    • 财政年份:
      2015
    • 负责人:
      YONEMURA TOSHIAKI
    • 依托单位:
    海外基金