study of nano-explosion reaction in solid phase at row temperature

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The photochemical chain reactions between organic compounds and halogens in solid phase at low temperature have been investigated. About the photochemical process of chlorine, the optical explosive phenomenon was observed in the acetylene chlorine mixture system. Furthermore we have found the phenomenon which can be called optical nano explosion with the huge quantum yield in butadiene-chlorine system. As a result, meaning of the difference between gas and solid phase was able to be clarified. In the photochemical process in acetone and the low-temperature solid phase of N2O5, new knowledge was also found out from the atmospheric chemistry.