Development of the Chemistry of Transition Metal Complexes UsingLithium Encapsulated Fullerene as a Ligand

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As a chemical modification of lithium cation encapsulated fullerene, [Li+@C_<60>], introduction of an organic moiety was performed. We succeeded in synthesis, isolation, and crystal structure analysis of a PCBM-type compound, [Li+@PCBM]. Synthesis of polynuclear complexes having several transition metal fragments on the [Li+@C_<60>] cage was also performed. We succeeded in isolation of dinuclear and hexanuclear iridium complexes of [Li+@C60]. In the case of the hexanuclear complex, the structure was determined by single crystal X-ray structure analysis.