Development of the nanoporous metal materials as the catalyst in the molecular transformation

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In this work, Suzuki-coupling and Heck reaction catalyzed by nanoporous Pd (PdNPore) which was fabricated by dealloying of the metallic glass alloy consists of Ni-Pd-P system were developed. This material can be used repeatedly without support, stabilizer, and ligand, because the morphology is the monolithic bulk metal. Furthermore, the one step synthetic method of formamides via aerobic oxidation in the presence of nanoporous Au (AuNPore) as a catalyst was developed. This reaction proceeds under ambient pressure, and methanol is preferentially-oxidized in the coexistence of alkylamine.