Development of Coupling Reactions Using Electrogenerated Active Organometallic

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The objective of research is the development of novel coupling reactions using electrogenerated organometallic species. We investigated several coupling reactions catalyzed by electrochemically generated palladium species. During the course of the study, we found that the choice of a co-oxidant and co-catalyst was highly significant for the control of the coupling reactions, and the polarity of the solvent was also important. After the optimization of these factors, we have achieved the development of the efficient coupling reactions leading to a wide variety of biaryls and diyne derivatives.