Fabrication of the functionalized solid metal oxide materials by controlling the void of the crystal lattice

由两个铑三核配合物、三个1，3-双（3-吡啶基乙炔基）苯或2.6-双（3-吡啶基乙炔基）吡啶桥联配体和六钨酸盐的合成，发现其对疏水分子如甲苯具有包封能力，而钯配合物和1，还可以合成3-双（4-吡啶基乙炔基）苯，并且可以观察到其对空隙对聚氧乙烯酸酯的包封能力。

Novel inorganic-organic hybrid composites consisting of two rhodium trinuclear complexes, three 1,3-bis(3-pyridylethynyl)benzene or 2.6-bis(3-pyridylethynyl)pyridine bridging ligands, and a hexatungstate were synthesized and its encapsulation ability toward the hydrophobic molecule, such as toluene, could be found. On the other hand, the molecular hexagon consisting of a palladium complex and a similar ligand of 1,3-bis(4-pyridylethynyl)benzene could also be synthesized, and its encapsulation ability of the void toward a polyoxometalate could be observed.