白金錯体の集合および包接制御による高輝度りん光性分子の創成

研究含(亚氨甲基)偶氮亚胺配体的聚亚甲基拱形铂(II)配合物的发光性质，以获得高磷光的铂(II)配合物，为开发高磷光功能材料提供重要信息，并为分子结构/堆积、缔合行为和光物理性质之间的相关性的基础研究提供重要信息。一份提交的出版物是关于溶液状态下的电阻浓度猝灭以及缔合行为和拱顶结构在均相溶液中聚集诱导的排放增强特性中的作用的第一个例子。在溶液和固态磷光中具有特殊耐热特性的第二份出版物正在进行中。

Research focuses on emission properties of polymethylene vaulted platinum(II) complexes bearing (iminomethyl)azolate ligand with rigid platform, to obtain highly phosphorescent Pt(II) complexes for the development of highly phosphorescent functional materials and provide significant information for basic research into the correlation between molecular structure/packing, association behavior, and photophysical properties. One submitted publication is the first example on resistant concentration quenching in solution state, and the role of the association behavior and vaulted structure for aggregation-induced emission enhancement properties in homogeneous solution. Second publication with specific heat-resistant properties in the phosphorescence at both solution and solid states is under progress.