白金錯体の集合および包接制御による高輝度りん光性分子の創成

重点研究了含（亚氨基甲基）唑配体的刚性平台的聚亚甲基拱形铂（II）配合物的发光性质，以期获得高磷光性的铂（II）配合物，为高磷光功能材料的开发提供重要的理论依据，并为研究分子结构/堆积、缔合行为和光物理性质之间的关系提供重要的基础信息。一个提交的出版物是第一个例子，在溶液状态下的电阻浓度猝灭，以及在均匀溶液中的聚集诱导的发射增强性能的缔合行为和拱形结构的作用。第二个出版物与特定的耐热性能的磷光在溶液和固体状态正在进行中。

Research focuses on emission properties of polymethylene vaulted platinum(II) complexes bearing (iminomethyl)azolate ligand with rigid platform, to obtain highly phosphorescent Pt(II) complexes for the development of highly phosphorescent functional materials and provide significant information for basic research into the correlation between molecular structure/packing, association behavior, and photophysical properties. One submitted publication is the first example on resistant concentration quenching in solution state, and the role of the association behavior and vaulted structure for aggregation-induced emission enhancement properties in homogeneous solution. Second publication with specific heat-resistant properties in the phosphorescence at both solution and solid states is under progress.