A study of guest molecular motion and host structure of multi-dimensional framework metal complex hosts formed with bridging cyano groups.

本研究已在订购中完成了关于客人分子运动和宿主结构之间关系的信息，该结构由金属复合体宿主分类形成，与桥接的陶瓷组。Main techniques used here were D12/D1H-NMR and X-ray diffraction。所收到的结果和信息如下：1. A computer program for analyzing molecular motion fromイイD12イエD1H-NMR powder patterns。本程序是为处理分子动力模式的各种类型而设计的。The thermally activated process of the out-of-plane motion of the benzene guest of [Cd（CN）（dmen）イD22イD2]イD2，[Cd（CN）イD24イD2] benzene clathrate， and molecular motion of a part of the metal complex host were clarified. 3。The information of benzene， toluene and ethylbenzene guest molecular motion in the cavity of a [N（CHイD23イエD2）イイD24イイD2] [CdイD23イエD2（CN）イD27イエD2] host， and their motional beManagement during the process of thermal decomposition was obtained。一些基本的M ... More 使用基本模式构建更复杂的分子运动的分子运动模式和一些技术，已经提出。A phase transition of [S（CHイイD23エD2）イイD23エD2][CdイD23エD2（CN）イD27エD2]·p-xylene clathrate， which is accompanied with change of p-xylene guest molecular motional mode and host structure， was found out. 5。The information of the motional behavior of the pyrrole guest， which is a polar molecule， in Cd（NHイD23エD2）イイD22エD2Ni（CN）イD24エD2 and Cd（en）Ni（CN）イD24エD2 host was obtained。这表明，螺旋桨客人的方向是在其大的重新导向运动中进行的，例如在其颗粒物中找到的，以及从主机-客人互动中找到的协同现象。客人分子运动是一个简单的、热激活的过程，已经成为这项研究的目标。在下一步中，现象，作为主机-来宾互动的协同效应的结果，从来宾分子运动和主机灵活性的角度来看，将成为主要目标。Less（低）

This research has been done in order to obtain information about the relation between guest molecular motion and host structure of multi-dimensional framework metal complex host clathrates formed with bridging cyano groups. Main techniques used here were ィイD12ィエD1H-NMR and X-ray diffraction. Obtained results and information are as follows.1. A computer program for analyzing molecular motion from ィイD12ィエD1H-NMR powder patterns. This program is designed for treating various types of molecular motional modes.2. The thermally activated process of the out-of-plane motion of the benzene guest of [Cd(CN)(dmen)ィイD22ィエD2]ィイD22ィエD2,[Cd(CN)ィイD24ィエD2] benzene clathrate, and molecular motion of a part of the metal complex host were clarified.3. The information of benzene, toluene and ethylbenzene guest molecular motion in the cavity of a [N(CHィイD23ィエD2)ィイD24ィエD2] [CdィイD23ィエD2(CN)ィイD27ィエD2] host, and their motional behavior during the process of thermal decomposition was obtained. Some fundamental m … More olecular motional modes and some techniques of constructing more complicated molecular motion using the fundamental modes have ,been presented.4. A phase transition of [S(CHィイD23ィエD2)ィイD23ィエD2][CdィイD23ィエD2(CN)ィイD27ィエD2]・p-xylene clathrate, which is accompanied with change of p-xylene guest molecular motional mode and host structure, was found out.5. The information of the motional behavior of the pyrrole guest, which is a polar molecule, in Cd(NHィイD23ィエD2)ィイD22ィエD2Ni(CN)ィイD24ィエD2 and Cd(en)Ni(CN)ィイD24ィエD2 host was obtained. It was shown that the orientation of the pyrrole guest is maintained in spite of its large reorientational motion like that found in its beazene clathrate, and a cooperative phenomenon coming from a host-guest interaction was found out.Guest molecular motion as a simple thermally activated process has been a target of this research so far. In a next step, phenomena, which appear as a result of cooperative effect of host-guest interaction coming from guest molecular motion and flexibility of host, will become a main target. Less