The Permeation of Water through Industrial Membrane Systems

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This project aims to understand the permeation of water through commercially relevant non-porous polymeric membranes. Permeation, solubility and diffusivity will be studied in the vicinity of the glass transition temperature to elucidate the changes in free volume that occur through this transition. Non-linear concentration gradients due to anisotropic swelling will be probed using novel laminated membrane systems. Water clustering will be evaluated by Fourier transform infrared spectroscopy and nuclear magnetic resonance. Results are proposed to be used to build a new phenomenological model of water permeation that can be used directly by engineers in the design of industrial membrane systems.