Heterometallic iron-molybdenum complexes for nitrogen activation

用于氮活化的异金属铁钼配合物

• 批准号: DE190100524
• 负责人: Dr Jamie Hicks
• 金额: $ 29.67万
• 依托单位: The Australian National University
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Early Career Researcher Award
• 财政年份: 2019
• 资助国家: 澳大利亚
• 起止时间: 2019-06-17 至 2022-12-31
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DE190100524
• 关键词: Heterometallic; iron; molybdenum; complexes; nitrogen

This project aims to develop a range of bio-inspired, mixed metal iron-molybdenum complexes that are capable of activating molecular nitrogen, N2, at ambient pressure and temperature. The activation of atmospheric N2 is performed on a multi-million tonne scale each year and is key to a number of industrial processes. The project expects to generate new knowledge in the area of organometallic chemistry, specifically with regards to molecular metal-metal bonding and subsequent reactivity towards the activation of N2. Expected outcomes include new and improved catalysts, which will provide significant financial benefits to industry, as well as benefiting the environment by reducing energy demand.

该项目旨在开发一系列仿生混合金属铁钼络合物，这些络合物能够在环境压力和温度下激活分子氮（N2）。大气中氮气的活化每年有数百万吨规模，是许多工业过程的关键。该项目期望在有机金属化学领域产生新知识，特别是关于分子金属-金属键合以及随后的氮气活化反应性。预期成果包括新的和改进的催化剂，这将为工业带来显着的经济效益，并通过减少能源需求来造福环境。