Small items of research equipment at the University of St Andrews. Supporting a new generation of Physical Sciences Research.

圣安德鲁斯大学的小型研究设备。

• 批准号: EP/K031252/1
• 负责人: Chris Hawkesworth
• 金额: $ 56.69万
• 依托单位: University of St Andrews
• 依托单位国家: 英国
• 项目类别: Research Grant
• 财政年份: 2012
• 资助国家: 英国
• 起止时间: 2012 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=EP%2FK031252%2F1
• 关键词: Small; items; research; equipment; University

A range of small equipment will be used to support and enhance activities of early career researchers and EPSRC funded fellows and PhD students:Groups in synthetic optical materials (SOM) and nanophotonics are developing materials and devices for all fields that benefit from tailored control of light matter interaction at the nanoscale, eg ultrathin flexible metamaterials (metaflex) embedding graphene layers with dynamically controllable optical response for imaging and cloaking to energy and bio-related applications and narrow linewidth lasers based on semiconductor optical amplifiers and narrow nanostructured mirrors, as optical interconnect for energy efficient data transfer and manipulation. Researchers in catalysis are developing more atom efficient syntheses and syntheses under benign conditions to provide a sustainable future for the UK. Furthermore, the rapid depletion of fossil fuels as a resource for energy and chemicals production necessitates a future change to increase the use of biomass. The most abundant renewable resource in this context is lignocellulosic biomass, which is much more plentiful than the alternative feedstocks such as sugars, starch, oils and fats. A diverse range of high quality facilities and research programs aimed at characterising for example novel materials, devices, different states of matter, biological materials, will be enhanced by the provision of eg improved variable temperature devices, modern computer interfaces and atmospheric control. These facilities support all of the physical sciences in St Andrews.Chemical Biology and Health will develop programs combining molecular biology, surface science and engineering in order to make new designer biocatalysts and expeditious access to designer natural product analogues for health and as tools for chemical biology by combining synthetic biology and synthetic chemistry. Furthermore, single-molecule microscopy techniques will be applied to elucidate molecular conformation, assess chemical reactions, achieve single molecule sensing, monitor relevant kinetics, reveal sample heterogeneity and detect transient species with an unprecedented level of detail.Mathematical computational activity will be enhanced by provision of new parallel computing facilities. In addition the new equipment will enhance the ability of multi-disciplinary groups in the schools of Psychology and Computer Science to develop and test new novel input and output devices, and c) explore how best to create, design and explain content with these input and output modalities.

一系列小型设备将用于支持和加强早期职业研究人员和EPSRC资助的研究员和博士生的活动：合成光学材料（SOM）和纳米光子学的研究小组正在开发适用于所有领域的材料和器件，这些材料和器件受益于在纳米尺度上对光物质相互作用的定制控制，例如柔性超材料（metaflex）嵌入石墨烯层，其具有动态可控的光学响应，用于对能量和生物相关应用以及基于半导体光放大器和窄纳米结构镜的窄线宽激光器进行成像和隐身，作为用于能量高效数据传输和操作的光学互连。催化领域的研究人员正在开发更多的原子效率合成和良性条件下的合成，为英国提供一个可持续的未来。此外，作为能源和化学品生产资源的化石燃料迅速枯竭，因此今后必须改变做法，增加生物量的使用。在这种情况下，最丰富的可再生资源是木质纤维素生物质，其比替代原料如糖、淀粉、油和脂肪丰富得多。一系列高质量的设施和研究计划，旨在表征例如新材料，设备，不同状态的物质，生物材料，将通过提供改进的变温设备，现代计算机接口和大气控制来加强。化学生物学和健康将开发结合分子生物学，表面科学和工程的项目，以使新的设计师生物催化剂和快速获得设计师天然产物类似物的健康和作为化学生物学的工具，通过结合合成生物学和合成化学。此外，单分子显微镜技术将应用于阐明分子构象、评估化学反应、实现单分子传感、监测相关动力学、揭示样品异质性和以前所未有的详细程度检测瞬时物种。此外，新设备将提高心理学和计算机科学学院多学科小组开发和测试新的输入和输出设备的能力，以及c）探索如何最好地创建，设计和解释这些输入和输出模式的内容。

项目成果

Geometrically Enforced Donor-Facilitated Dehydrocoupling Leading to an Isolable Arsanylidine-Phosphorane

• DOI: 10.1021/ja502625z
• 发表时间: 2014-04-30
• 期刊: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
• 影响因子: 15
• 作者: Chalmers, Brian A.;Buehl, Michael;Kilian, Petr
• 通讯作者: Kilian, Petr

A simple access to transition metal cyclopropenylidene complexes.

• DOI: 10.1039/c4cc10375k
• 发表时间: 2015-03
• 期刊: Chemical communications
• 影响因子: 4.9
• 作者: Yannick D. Bidal;M. Lesieur;M. Melaimi;D. Cordes;A. Slawin;G. Bertrand;C. Cazin

Extending the Family of V(4+) S=(1/2) Kagome Antiferromagnets.

• DOI: 10.1002/anie.201506869
• 发表时间: 2015-10
• 期刊: Angewandte Chemie
• 作者: L. Clark;F. Aidoudi;C. Black;K. Arachchige;A. Slawin;R. Morris;P. Lightfoot

Synthesis and Characterization of Gold(I) Complexes of Dibenzotropylidene-Functionalized NHC Ligands (Trop-NHCs)

二苯并亚甲基官能化 NHC 配体 (Trop-NHC) 金 (I) 配合物的合成和表征

• DOI: 10.1021/om501093s
• 发表时间: 2014
• 期刊: Organometallics
• 影响因子: 2.8
• 作者: Brill M

Synthesis of selectively fluorinated cyclohexanes: The observation of phenonium rearrangements during deoxyfluorination reactions on cyclohexane rings with a vicinal phenyl substituent

• DOI: 10.1016/j.jfluchem.2015.08.003
• 发表时间: 2015-11-01
• 期刊: JOURNAL OF FLUORINE CHEMISTRY
• 影响因子: 1.9
• 作者: Bykova, Tetiana;Al-Maharik, Nawaf;O'Hagan, David
• 通讯作者: O'Hagan, David