Overseas travel to perform in-situ STM experiments at Aarhus University

出国前往奥尔胡斯大学进行原位STM实验

• 批准号: EP/S013946/1
• 负责人: Alex Walton
• 金额: $ 1.02万
• 依托单位: University of Manchester
• 依托单位国家: 英国
• 项目类别: Research Grant
• 财政年份: 2018
• 资助国家: 英国
• 起止时间: 2018 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=EP%2FS013946%2F1
• 关键词: Overseas; travel; perform; situ; STM

Nitrogen doped graphene (N-graphene) is a sheet of graphene with some of the carbon atoms swapped with nitrogen. This material has shown great promise for a number of technological applications - most notably as an electrocatalyst (something that makes an electrochemical reaction more efficient, for example increasing the performance of a battery). However, the "doping" process (how the nitrogen atoms integrate into the carbon lattice and where exactly they go) is not well understood. Gaining a fundamental understanding of how this process works and how to control it would allow researchers and ultimately industry to "tailor" their nitrogen doped graphene for optimal performance. This is a big challenge as it involves understanding how the material evolves on the atomic scale.This proposal seeks to build a new collaboration with a world-leading research group at Aarhus University, Denmark. They are specialists in an advanced microscopy technique called Scanning Tunnelling Microscopy. This allows a sample to be seen in atomic resolution, so we can see exactly where the nitrogen atoms are in the graphene. This is highly complementary with the PI's own X-Ray spectroscopy research, which provides information on the chemical nature of the nitrogen dopants. The combination of the two will allow for a full, atomic-scale picture of how nitrogen incorporates into the graphene and give us clues on how to control this process. This grant will allow the PI to travel to Aarhus University several times over the course of a year to conduct experiments in their lab and correlate the results with experiments done in his home lab.

氮掺杂石墨烯（N-graphene）是一种石墨烯片，其中一些碳原子与氮交换。这种材料在许多技术应用中显示出巨大的前景-最值得注意的是作为电催化剂（使电化学反应更有效，例如提高电池的性能）。然而，“掺杂”过程（氮原子如何融入碳晶格以及它们到底去了哪里）还没有很好的理解。对这一过程的工作原理以及如何控制它有了基本的了解，将使研究人员和最终的工业界能够“定制”他们的氮掺杂石墨烯，以获得最佳性能。这是一个巨大的挑战，因为它涉及到了解材料如何在原子尺度上演变。这项提议旨在与丹麦奥胡斯大学的一个世界领先的研究小组建立新的合作关系。他们是一种先进的显微镜技术的专家，称为扫描隧道显微镜。这允许以原子分辨率看到样品，因此我们可以确切地看到氮原子在石墨烯中的位置。这与PI自己的X射线光谱研究高度互补，该研究提供了有关氮掺杂剂化学性质的信息。两者的结合将允许氮如何结合到石墨烯中的完整的原子尺度图片，并为我们提供如何控制这一过程的线索。这笔拨款将允许PI在一年内多次前往奥胡斯大学，在他们的实验室进行实验，并将结果与他的家庭实验室进行的实验相关联。

项目成果

Universal shape of graphene nanobubbles on metallic substrate

金属基底上石墨烯纳米气泡的通用形状

• DOI: 10.1039/d1cp05902e
• 发表时间: 2022
• 期刊: Physical Chemistry Chemical Physics
• 影响因子: 3.3
• 作者: Aslyamov T

Oxide-mediated nitrogen doping of CVD graphene and their subsequent thermal stability

• DOI: 10.1088/1361-6528/acedb5
• 发表时间: 2023-08
• 期刊: Nanotechnology
• 影响因子: 3.5
• 作者: Khadisha M Zahra;Conor Byrne;Zheshen Li;Kerry Hazeldine;A. Walton