Terahertz-frequency sensors for atmospheric chemistry and space research (renewal)

用于大气化学和空间研究的太赫兹频率传感器(更新)

基本信息

  • 批准号:
    MR/Y011775/1
  • 负责人:
  • 金额:
    $ 75.42万
  • 依托单位:
  • 依托单位国家:
    英国
  • 项目类别:
    Fellowship
  • 财政年份:
    2024
  • 资助国家:
    英国
  • 起止时间:
    2024 至 无数据
  • 项目状态:
    未结题

项目摘要

When we look into space with existing infrared, radio and microwave sensors, we see less than half the light in our galaxy. Most of this "missing" light lies in the terahertz (THz) or far-infrared part of the spectrum (1-10 THz, 30-300 micron wavelength). Indeed, the "invisible" gases in the Earth's atmosphere and the "dark" dust and gas clouds between stars all glow with distinctive THz fingerprints, providing a wealth of hidden information urgently needed by atmospheric and space scientists.Despite this great potential, existing THz sensor systems are too large, fragile and complex for most applications outside the laboratory and lack the sensitivity needed for studying reactive gases. Furthermore, this lack of technological readiness limits the prospects for THz systems being deployed in space. A short time-window is available for the UK to invest in real-world demonstrations of key THz components and sensing techniques and secure a place in forthcoming space missions, for example, via the ESA Earth Explorer 12 (or 13) programmes. Without this, the potential for a UK researcher to lead the world in this emerging area will be lost.In this fellowship, I am overcoming limitations of THz gas sensors by developing high-sensitivity systems based on quantum-cascade lasers (QCLs) - highly compact sources of THz radiation, which yield >1000 times the power of any similar-sized device. I have developed new project partnerships to exploit extremely fast and stable TeraFET detectors, enabling tiny changes in gas concentrations to be measured in real time. Unlike previous THz-QCL-based gas-sensing schemes, I am developing high-precision analytical chemistry techniques, and have developed the first custom-made multi-pass gas cell in which THz radiation passes repeatedly through the gas under study, yielding an estimated 100x improvement in sensitivity.In this Renewal phase of the fellowship, I will adapt my internationally-leading THz gas sensing instrumentation to use an ultraviolet (UV) laser to simulate the behaviour of gases in the upper atmosphere, and "trigger" chemical reactions at a precise time. This will allow me to study the behaviour of volatile organic compounds (VOCs) such as formaldehyde as they react in the atmosphere, and resolve the huge uncertainties in the effect of these reactions on climate change. By developing fast detection schemes, I will provide the means to study the concentrations of industrial and agricultural pollutants in real time, and I will investigate the potential for UV-pump/THz-probe "step-scan" detection technique to probe the dynamics of upper-atmospheric reactions on microsecond timescales.Through my partnership with RAL Space, I have demonstrated the world's first integration of THz QCLs with precision-micromachined waveguides, antennas, and "on-chip" stabilisation subsystems. This Renewal phase will provide a further step-change in capability, by developing the first satellite-compatible THz laser stabilisation schemes, through the use of integrated power and frequency control systems, within "sugarcube"-sized satellite-compatible modules. I will work with RAL Space, and TK Instruments to demonstrate this capability within a space-qualified cryocooler, including bespoke THz optics and calibration targets, on a satellite-test "breadboard", underpinning its future deployment on a satellite platform.To sustain my research vision, and establish THz sensing as a key tool for atmospheric and space research, I will work closely with my project partners to secure follow-on funding for THz chemistry, Earth observation and critical satellite payload instrumentation. I will produce a roadmap for in-orbit deployment, and commercialisation, including developing the science and technology case for a European Space Agency satellite mission through the Earth Explorer programme.
当我们用现有的红外线、无线电和微波传感器观察太空时,我们看到的光还不到银河系的一半。大多数“丢失”的光位于太赫兹(THz)或光谱的远红外部分(1-10太赫兹,30-300微米波长)。事实上,地球大气中“看不见”的气体和恒星之间“黑暗”的尘埃和气体云都发出独特的太赫兹指纹,提供了大气和空间科学家迫切需要的大量隐藏信息。尽管有巨大的潜力,但现有的太赫兹传感器系统对于实验室以外的大多数应用来说过于庞大、脆弱和复杂,并且缺乏研究活性气体所需的灵敏度。此外,缺乏技术准备限制了太赫兹系统在空间部署的前景。英国有一个短暂的时间窗口,可以投资于关键太赫兹组件和传感技术的实际演示,并确保在即将到来的太空任务中占有一席之地,例如,通过欧空局地球探测器12(或13)计划。如果没有这一点,英国研究人员在这一新兴领域领导世界的潜力将会丧失。在这项研究中,我通过开发基于量子级联激光器(qcl)的高灵敏度系统来克服太赫兹气体传感器的局限性-量子级联激光器是高度紧凑的太赫兹辐射源,其产生的功率是任何类似尺寸设备的1000倍。我已经开发了新的项目合作伙伴关系,以开发极其快速和稳定的TeraFET探测器,使气体浓度的微小变化能够实时测量。与以前基于太赫兹qcl的气体传感方案不同,我正在开发高精度分析化学技术,并开发了第一个定制的多通道气体池,其中太赫兹辐射反复通过所研究的气体,估计灵敏度提高了100倍。在奖学金的这个更新阶段,我将调整我的国际领先的太赫兹气体传感仪器,使用紫外线(UV)激光来模拟上层大气中气体的行为,并在精确的时间“触发”化学反应。这将使我能够研究挥发性有机化合物(VOCs)(如甲醛)在大气中发生反应时的行为,并解决这些反应对气候变化影响的巨大不确定性。通过开发快速检测方案,我将提供实时研究工业和农业污染物浓度的手段,我将研究紫外线泵/太赫兹探针“步进扫描”检测技术在微秒时间尺度上探测高层大气反应动力学的潜力。通过与RAL Space的合作,我展示了世界上第一个将太赫兹量子激光器与精密微机械波导、天线和“片上”稳定子系统集成在一起的产品。通过在“方糖”大小的卫星兼容模块内使用综合功率和频率控制系统,通过开发第一个卫星兼容太赫兹激光稳定方案,该更新阶段将提供进一步的能力变化。我将与RAL空间公司和TK仪器公司合作,在卫星测试“面包板”上演示这种能力,包括定制的太赫兹光学器件和校准目标,为其未来在卫星平台上的部署奠定基础。为了维持我的研究愿景,并将太赫兹传感作为大气和空间研究的关键工具,我将与我的项目伙伴密切合作,以确保太赫兹化学、地球观测和关键卫星有效载荷仪器的后续资金。我将为在轨部署和商业化制定路线图,包括通过地球探索者计划为欧洲航天局的卫星任务开发科学和技术案例。

项目成果

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Alexander Valavanis其他文献

Process and material constraints of additive manufacturing for fabrication of terahertz quasi-optical components
太赫兹准光学元件制造的增材制造工艺和材料限制
  • DOI:
    10.1016/j.apmt.2025.102619
  • 发表时间:
    2025-02-01
  • 期刊:
  • 影响因子:
    6.900
  • 作者:
    Luke Phillips;Alexander Valavanis;Andrew D. Burnett;Robert Kay;Russell Harris;Ehab Saleh
  • 通讯作者:
    Ehab Saleh

Alexander Valavanis的其他文献

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{{ truncateString('Alexander Valavanis', 18)}}的其他基金

Terahertz-frequency sensors for atmospheric chemistry and space research
用于大气化学和空间研究的太赫兹频率传感器
  • 批准号:
    MR/S016929/1
  • 财政年份:
    2019
  • 资助金额:
    $ 75.42万
  • 项目类别:
    Fellowship

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