Long-lived Radionuclides in the Surface Environment (LO-RISE)- Mechanistic Studies of Speciation, Environmental Transport and Transfer

地表环境中的长寿命放射性核素 (LO-RISE) - 形态、环境传输和转移的机制研究

• 批准号: NE/L00027X/1
• 负责人: J Mosselmans
• 金额: $ 1.39万
• 依托单位: Diamond Light Source
• 依托单位国家: 英国
• 项目类别: Research Grant
• 财政年份: 2013
• 资助国家: 英国
• 起止时间: 2013 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=NE%2FL00027X%2F1
• 关键词: Long; lived; Radionuclides; Surface; Environment

The impact of radioactivity on humans and the wider environment is controlled by the behaviour of the radionuclides in groundwaters, soils and sediments, and this behaviour is dictated by the quantities of radionuclides, and their chemical forms. We will study some of the radionuclides which are particularly important because they are potentially present in relatively large quantities, are environmentally mobile, and are readily taken up by living organisms. The main radionuclides we are going to study are:Carbon-14, which occurs in nature, but was produced back in the 1960s and 60s through nuclear weapons testing, and is also present in nuclear wastes; and Uranium (together with its decay product radium) which is present in nature, and also in some nuclear wastes.We will use four areas of the UK which contain elevated levels of these radionuclides as our study sites. These are South Terras (an old uranium mine in Cornwall), the Needle's Eye (a uranium mineral vein in SW Scotland), the Esk Estuary in NW England, and offshore sediments in the NE Irish Sea. At these last two sites, the sediments contain elevated levels of radioactivity from authorised Sellafield discharges, mainly in the 1970s. As well as studying how radioactivity occurs in, and moves through, the soils, waters, plants and (in the offshore sediments) animals, we want to understand the environmental and biological processes which control this movement. To do this, we will do a series of laboratory experiments, looking at the way soil/sediment conditions influence the radionuclide concentrations in solution, the form of the radionuclides in the solution, the way radionuclides are taken up into plants and animals, and the way they are distributed in plant tissues. We will use the results from our field and laboratory studies to develop and test mathematical models of radionuclide transport and transfer processes. These are important because they allow us to predict behaviour, rather than having to make measurements. These predictive models can be used in assessing environmental impacts, cleaning up contaminated land and predicting the long term impact of radioactive waste disposals.

放射性对人类和更广泛的环境的影响取决于放射性核素在地下水、土壤和沉积物中的行为，而这种行为又取决于放射性核素的数量及其化学形式。我们将研究一些特别重要的放射性核素，因为它们可能存在于相对大量的环境中，是移动的，并且很容易被生物体吸收。我们将研究的主要放射性核素是：碳-14，它存在于自然界中，但早在1960年代和60年代通过核武器试验产生，也存在于核废料中;铀（连同其衰变产物镭），它存在于自然界中，也存在于一些核废料中。我们将使用英国四个含有高水平这些放射性核素的地区作为我们的研究地点。它们是南特拉斯（康沃尔郡的一个老铀矿）、针眼（苏格兰西南部的一个铀矿脉）、英格兰西北部的埃斯克河口和东北爱尔兰海的近海沉积物。在这最后两个地点，沉积物中含有来自塞拉菲尔德授权排放的高水平放射性物质，主要是在20世纪70年代。除了研究放射性如何在土壤、沃茨、植物和（近海沉积物中的）动物中发生和移动之外，我们还想了解控制这种移动的环境和生物过程。为此，我们将进行一系列实验室实验，研究土壤/沉积物条件如何影响溶液中的放射性核素浓度，溶液中放射性核素的形式，放射性核素被植物和动物吸收的方式，以及它们在植物组织中的分布方式。我们将利用我们的实地和实验室研究结果，开发和测试放射性核素迁移和转移过程的数学模型。这些很重要，因为它们使我们能够预测行为，而不是进行测量。这些预测模型可用于评价环境影响、清理污染土地和预测放射性废物处置的长期影响。

项目成果

Np(V) sorption and solubility in high pH calcite systems

高 pH 方解石系统中的 Np(V) 吸附和溶解度

• DOI: 10.1016/j.chemgeo.2018.06.016
• 发表时间: 2018
• 期刊: Chemical Geology
• 影响因子: 3.9
• 作者: Smith K

Impacts of Repeated Redox Cycling on Technetium Mobility in the Environment.

• DOI: 10.1021/acs.est.7b02426
• 发表时间: 2017-12
• 期刊: Environmental science & technology
• 影响因子: 11.4
• 作者: N. Masters-Waage;K. Morris;J. Lloyd;S. Shaw;W. J.Frederick;Mosselmans;C. Boothman;P. Bots;Athanasios Rizoulis;F. Livens;G. Law