Development of the Tripuhyite Technology for Remediating Antimony-Contaminated Waters and Recovering Antimony

三磷矿修复锑污染水体及回收锑技术的开发

• 批准号: NE/P003095/1
• 负责人: Karen Hudson-Edwards
• 金额: $ 1.89万
• 依托单位: Birkbeck, University of London
• 依托单位国家: 英国
• 项目类别: Research Grant
• 财政年份: 2016
• 资助国家: 英国
• 起止时间: 2016 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=NE%2FP003095%2F1
• 关键词: Development; Tripuhyite; Technology; Remediating; Antimony

Antimony (Sb) is classified as a priority pollutant in the United States and European Union because ingestion of Sb-bearing fluids or inhalation of Sb-bearing particles can lead to lung, heart and stomach diseases. The major source of Sb in the environment is mine wastes, which contain 10s to 100s of parts per million of Sb. It has been estimated that the quantity of solid mine waste generated throughout the world matches that of Earth materials moved by fundamental global geological processes, at approximately several thousand million tonnes per year. This figure is predicted to grow over the next 100 years due to increasing demand for mineral resources, coupled with lower ore grades. Therefore, the amount of mine waste-derived Sb will also increase. Dissolution of the Sb-bearing materials in mine wastes can lead to Sb contamination of waters and to Sb uptake in plants and animals (including humans). Though precise numbers of people directly affected by mine waste-derived Sb are not available, they are likely to be in the range of 10s to 100s of thousands, given that 10,000 inhabitants are impacted in the Sb mining area of Xikuangshan, China alone. Other sources of Sb in the environment are largely industrial, including flame retardants, batteries, chemical, ceramics and glass. Mining companies, government bodies and others responsible for providing clean water are required to reduce the risk of Sb contamination by remediating the water to reduce Sb concentrations to levels considered safe by regulatory authorities. This risk can be mitigated, and Sb-contaminated waters remediated, by the precipitation of minerals, especially those that are relatively insoluble and have low bioaccessibility (i.e., low ability to be taken up by plants, animals and humans). The mineral tripuhyite (iron antimonate oxide, FeSbO4) is such a mineral, and it could therefore be used for remediation and improvement of ecosystem and human health in Sb-contaminated environments worldwide. In addition, tripuhyite could be used as a means of recovering and recycling the Sb for other uses (e.g., semiconductor devices, metal alloys, flame-retardant materials, paints, enamels, glass, pottery). For this Pathfinder project we propose to develop the 'Tripuhyite Technology', a method for precipitating and stabilizing tripuhyite for use in remediation of antimony-contaminated mine waters and for recovery of Sb for industrial uses. The Pathfinder proposal aims to (i) evaluate the market opportunity and commercial need in order to develop a business model for developing the tripuhyite technology and (ii) carry out 'Technical Milestone I' work to determine the feasibility of the Tripuhyite Technology. These aims will be achieved by commissioning market research and conducting scientific experiments. The results of the Pathfinder project will increase the likelihood of commercial adoption of the Tripuhyite Technology by providing comprehensive experimental data on mechanisms for tripuhyite precipitation and scale-up of the technology and opportunities for engagement with additional project partners and potential stakeholders.

锑（Sb）在美国和欧盟被列为优先污染物，因为摄入含Sb的液体或吸入含Sb的颗粒可导致肺、心脏和胃疾病。环境中锑的主要来源是矿山废物，其中含有百万分之10到100的锑。据估计，全世界产生的固体矿山废物的数量与基本全球地质过程移动的地球材料的数量相匹配，每年约为数十亿吨。由于对矿产资源的需求不断增加，加上矿石品位降低，预计这一数字将在未来100年内增长。因此，从矿山废物中提取锑的量也将增加。含锑材料在矿山废物中的溶解可导致沃茨的锑污染以及植物和动物（包括人类）对锑的吸收。虽然无法获得直接受矿山废物产生的锑影响的确切人数，但鉴于仅在中国锡矿山的锑矿区就有1万名居民受到影响，因此这些人数可能在1万至10万人之间。环境中锑的其他来源主要来自工业，包括阻燃剂、电池、化学品、陶瓷和玻璃。矿业公司、政府机构和其他负责提供清洁水的机构必须通过补救水来降低锑污染的风险，将锑浓度降低到监管机构认为安全的水平。通过沉淀矿物质，特别是那些相对不溶性和生物可及性低的矿物质（即，被植物、动物和人类吸收的能力低）。矿物三锑酸铁（铁锑酸盐氧化物，FeSbO4）就是这样的矿物，因此它可以用于修复和改善全球Sb污染环境中的生态系统和人类健康。此外，锑铅矿可以用作回收和再循环Sb用于其他用途的手段（例如，半导体器件、金属合金、阻燃材料、油漆、搪瓷、玻璃、陶器）。对于这个开拓者项目，我们建议开发“Tripuhyite技术”，一种沉淀和稳定tripuhyite的方法，用于修复锑污染的矿井沃茨和回收锑用于工业用途。开拓者建议书旨在（i）评估市场机会和商业需求，以制定开发Tripuhyite技术的商业模式，以及（ii）开展“技术里程碑I”工作，以确定Tripuhyite技术的可行性。这些目标将通过委托市场研究和进行科学实验来实现。开拓者项目的成果将通过提供关于三水石膏沉淀机制和扩大技术规模的全面实验数据以及与其他项目伙伴和潜在利益攸关方接触的机会，增加三水石膏技术在商业上采用的可能性。