Endometallated bis(carboranes) as Novel Catalysts

内金属化双（碳硼烷）作为新型催化剂

• 批准号: 1797694
• 金额: --
• 依托单位: Heriot-Watt University
• 依托单位国家: 英国
• 项目类别: Studentship
• 财政年份: 2016
• 资助国家: 英国
• 起止时间: 2016 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=studentship-1797694
• 关键词: Endometallated; bis; carboranes; Novel; Catalysts

Endometallated bis(carboranes) have potential as catalysts in a number of reactions, but we will focus initially on alkene isomerisation, alkene hydrogenation and the hydrosilylation of acetophenone and styrene. The project will explore the many ways in which these catalysts can be chemically modified to optimise each reaction and therefore it will involve the synthesis, spectroscopic and structural characterisation of potential catalysts, followed by their catalytic testing.

封端的双（碳硼烷）在许多反应中具有作为催化剂的潜力，但我们将首先集中在烯烃异构化，烯烃氢化和苯乙酮和苯乙烯的氢化硅烷化。该项目将探索这些催化剂可以进行化学改性以优化每个反应的多种方法，因此它将涉及潜在催化剂的合成，光谱和结构表征，然后进行催化测试。