Femtosecond Diffraction Studies of Shock and Ramp-Compressed Matter

冲击和斜坡压缩物质的飞秒衍射研究

• 批准号: 1963728
• 金额: --
• 依托单位: University of Oxford
• 依托单位国家: 英国
• 项目类别: Studentship
• 财政年份: 2016
• 资助国家: 英国
• 起止时间: 2016 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=studentship-1963728
• 关键词: Femtosecond; Diffraction; Studies; Shock; Ramp

The project aims to use the femtosecond pulses from a hard x-ray free electron laser (the Linac Coherent Light Source - LCLS at SLAC) to measure deformation and structure of matter shock or ramp compressed to multi-megabar pressures, accessing regions of phase space inaccessible to study with diamond anvil cells. The experiments will be augmented with multi-million atom molecular dynamics simulations coupled with diffraction simulations. The research has both applied and fundamental aspects. From the fundamental point of view a significant amount of matter in the visible universe exists in states of pressure and temperature inaccessible to many laboratory experiments - e.g. the interior of the large planets in our own solar system, and those that have been discovered orbiting other stars (exoplanets). Recreating and understanding the conditions existing in these regions is of fundamental interest. From the applied point of view it is as yet unknown what materials, once produced at high temperature and pressure, may be metastable (and of commercial use) at ambient conditions. For example, it is well known that diamond is metastable (it is not the state with the lowest free energy), however, the enthalpy barrier between it and the graphite phase is huge, and it thus exists under ambient conditions, and has considerable industrial impact. Thus the overall field of explore matter under novel conditions, learning its structure, and then bringing it back (if possible) to ambient conditions could be of considerable impact.The aims of the project are to better understand, at the lattice level, the physics of high-strain rate plasticity and polymorphic phase transformations. This will be undertaken both by theoretical investigation (molecular dynamics simulations) and via experiments employing femtosecond x-ray diffraction of materials shock or ramp compressed by high power laser ablation. The aim is, for several classes of material, to better understand how, under the uniaxial strain conditions applied by laser ablation, the material relieves the shear stresses to flow towards the hydrostatic. We know that, depending upon the material, this can happen via dislocation generation and flow, via twinning, and via polymorphic phase transitions. However, what actually happens at the lattice level, and at the mesoscale of individual grains, has yet to be explored in any detail. In this project the student will study both simple metals and more complex targets to start to unravel this complicated set of phenomena. This project is directly related to the laser-plasmas and fusion EPSRC theme. For example the physics is encompassed under EPSRC grant EP/J017256/1 The Creation and Diagnosis of Solid-State Matter at Multi-TeraPascal Pressures. This is 50% funded by AWE, and we will also collaborate closely with LLNL in the USA.

该项目旨在使用来自硬X射线自由电子激光器（直线加速器相干光源-SLAC的LCLS）的飞秒脉冲来测量压缩到多兆巴压力的物质冲击或斜坡的变形和结构，访问无法使用金刚石砧座细胞研究的相空间区域。实验将增加数百万原子分子动力学模拟加上衍射模拟。研究既有应用方面的，也有基础方面的。从基本的观点来看，可见宇宙中大量的物质存在于许多实验室实验无法达到的压力和温度状态中-例如，我们太阳系中的大行星的内部，以及那些被发现绕着其他恒星（系外行星）运行的行星。重建和了解这些地区的现有条件具有根本意义。从应用的观点来看，目前还不知道什么材料一旦在高温高压下生产，在环境条件下可能是亚稳定的（并具有商业用途）。例如，众所周知，金刚石是亚稳态的（它不是具有最低自由能的状态），然而，它与石墨相之间的焓垒是巨大的，因此它存在于环境条件下，并具有相当大的工业影响。因此，在新的条件下探索物质，了解其结构，然后将其带回（如果可能的话）环境条件的整个领域可能会产生相当大的影响。该项目的目的是在晶格水平上更好地理解高应变率塑性和多晶相变的物理学。这将通过理论研究（分子动力学模拟）和采用飞秒X射线衍射的材料冲击或高功率激光烧蚀压缩斜坡的实验来进行。其目的是，对于几类材料，以更好地了解如何在激光烧蚀施加的单轴应变条件下，材料释放剪切应力流向流体静力学。我们知道，根据材料的不同，这可以通过位错的产生和流动，通过孪生，以及通过多晶相变发生。然而，在晶格水平和单个颗粒的介观尺度上实际发生了什么，还有待于详细探索。在这个项目中，学生将研究简单的金属和更复杂的目标，开始解开这一系列复杂的现象。该项目与激光等离子体和聚变EPSRC主题直接相关。例如，物理学包含在EPSRC资助EP/J 017256/1在多太帕斯卡压力下固态物质的产生和诊断中。这是由AWE资助的50%，我们还将与美国的LLNL密切合作。

项目成果

Molecular dynamics simulations of grain interactions in shock-compressed highly textured columnar nanocrystals

• DOI: 10.1103/physrevmaterials.3.083602
• 发表时间: 2019-08
• 期刊: Physical Review Materials
• 影响因子: 3.4
• 作者: P. Heighway;D. McGonegle;N. Park;A. Higginbotham;J. Wark

Nonisentropic Release of a Shocked Solid.

• DOI: 10.1103/physrevlett.123.245501
• 发表时间: 2019-12
• 期刊: Physical review letters
• 影响因子: 8.6
• 作者: P. Heighway;M. Sliwa;D. McGonegle;C. Wehrenberg;C. Bolme;J. Eggert;A. Higginbotham;A. Lazicki;H. J. Lee;B. Nagler;Hye-Sook Park;R. Rudd;Raymond F. Smith;M. Suggit;D. Swift;F. Tavella;B. Remington;J. Wark