Electron transfer in hydrogen bonded metal-organic materials.

氢键金属有机材料中的电子转移。

• 批准号: 2447951
• 金额: --
• 依托单位: University of Huddersfield
• 依托单位国家: 英国
• 项目类别: Studentship
• 财政年份: 2020
• 资助国家: 英国
• 起止时间: 2020 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=studentship-2447951
• 关键词: Electron; transfer; hydrogen; bonded; metal

Hydrogen bonds are non-covalent interactions, but they can be relatively strong. The directionality of the hydrogen bond makes it suitable for the design of self-assembled supramolecular architectures, which can be easier to process than materials with covalent interactions. Recent studies have shown that charge transport through hydrogen bonds can be as efficient as through pi-bonds. This project will develop self-assembled metal-organic hydrogen bonded materials that have interesting charge transport properties, which incorporate metal-metal quadruple bonds. The designed synthesis of hydrogen bonded conductive compounds is likely to lead to a new class of electro-active hybrid materials.

氢键是非共价相互作用，但它们可以相对较强。氢键的方向性使其适合于自组装超分子结构的设计，这种结构比具有共价相互作用的材料更容易加工。最近的研究表明，通过氢键的电荷传输可以和通过pi键的电荷传输一样有效。该项目将开发具有有趣的电荷传输性能的自组装金属-有机氢键材料，其中包括金属-金属四键。氢键导电化合物的设计合成很可能导致一类新型的电活性杂化材料。