Low-coordinate main-group chemistry: Phosphorus and Borondoped aromatic compounds

低配位主族化学：磷和硼掺杂芳香族化合物

• 批准号: 2583304
• 金额: --
• 依托单位: University of Edinburgh
• 依托单位国家: 英国
• 项目类别: Studentship
• 财政年份: 2021
• 资助国家: 英国
• 起止时间: 2021 至 无数据
• 项目状态: 未结题
• 来源: https://gtr.ukri.org/projects?ref=studentship-2583304
• 关键词: Low; coordinate; main; group; chemistry

This project will focus on the design, synthesis, reactivity and electronic properties of main-groupelement doped aromatic hydrocarbons. Our ambition is to generate fundamental understanding of reactivity, bonding and electronic structure in such compounds and to develop new classes of heterocycles that are relevant to materials chemistry (e.g. as emissive or conducting materials).The project will build on previous work in the Cowley group, which has explored the reactivity of P=B double bonds and established phosphaborenes as reagents for the simultaneous incorporationof phosphorus and boron into unsaturated organic compounds (see for example: Angew. Chem. Int.Ed., 2017, 56, 99539957).

该项目将重点研究主族元素掺杂芳烃的设计、合成、反应活性和电子性能。我们的目标是对此类化合物的反应性、成键和电子结构产生基本的了解，并开发与材料化学（例如作为发射或导电材料）相关的新型杂环化合物。该项目将建立在考利小组先前的工作基础上，该小组探索了 P=B 双键的反应性，并建立了磷硼烯作为将磷和硼同时掺入化合物中的试剂。 不饱和有机化合物（例如参见：Angew. Chem. Int.Ed., 2017, 56, 99539957）。