Radicals in unconventional media - improving the sustainability of radical reactions through next generation ionic liquid radical chemistry

非常规介质中的自由基 - 通过下一代离子液体自由基化学提高自由基反应的可持续性

• 批准号: DP140100036
• 负责人: Prof Carl Schiesser
• 金额: $ 22.36万
• 依托单位: The University of Melbourne
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2014
• 资助国家: 澳大利亚
• 起止时间: 2014-01-01 至 2016-12-31
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP140100036
• 关键词: Radicals; unconventional; media; improving; sustainability

Despite significant advances over the past few decades, many free radical reactions are still carried out in organic solvents that are often toxic, flammable, difficult to recycle and employ undesirable reagents. It is timely that new free radical chemistry be developed that moves away from this "conventional" landscape. This proposal will develop a fundamental understanding of how free radicals interact with, and react in, (unconventional) ionic liquid solvents. This understanding will lead, in turn, to the development of new, more efficient, free radicals methods for the preparation of important materials that include biomolecules. Reduced environmental impact of free radical chemistry is the ultimate aim of this work.

尽管在过去的几十年里取得了重大进展，但许多自由基反应仍然在有机溶剂中进行，这些溶剂通常有毒、易燃、难以回收并且使用不需要的试剂。这是及时的，新的自由基化学被开发出来，远离这种“传统”的景观。该提案将发展自由基如何与（非常规）离子液体溶剂相互作用和反应的基本理解。这种理解将导致，反过来，新的，更有效的，自由基的方法制备重要的材料，包括生物分子的发展。减少自由基化学对环境的影响是这项工作的最终目标。