'Inverse' Coordination: A New Design Concept in Supramolecular Inorganic Chemistry

“逆”配位：超分子无机化学的新设计理念

• 批准号: EP/D076889/1
• 负责人: Robert Mulvey
• 金额: $ 52万
• 依托单位: University of Strathclyde
• 依托单位国家: 英国
• 项目类别: Research Grant
• 财政年份: 2006
• 资助国家: 英国
• 起止时间: 2006 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=EP%2FD076889%2F1
• 关键词: Inverse; Coordination; New; Design; Concept

While organic hosts for the coordination of anions have been extensively studied in the past few decades, studies of inorganic counterparts (whose frameworks are based predominantly on non-carbon atoms) have been much rarer. Indeed, the potentially general usefulness of inorganic systems of this type in anion coordination and supramolecular chemistry has not been realised, despite the fact that inorganic hosts frequently offer far greater affinity for anions than organic relatives (particularly those containing Lewis acidic metal atoms). In establishing a new collaboration, this proposal seeks to harness the expertise of two of the UK's leading researchers in main group chemistry in the development and exploitation of the new synthetic concept of inverse coordination of salt lattices, in which a range of elegant metal-based acceptors will be used as anion hosts. A major area of interest is the rational design of supramolecular main group assemblies using the concept of inverse coordination. In addition to providing the means for the stabilisation of unusual inorganic and organometallic anions, the immobilisation of the anions of simple salts by metal-based inverse ligands provides a novel approach to fast-ion conductors.

虽然在过去的几十年里，用于阴离子配位的有机主体已经被广泛研究，但对无机对应物（其框架主要基于非碳原子）的研究要少得多。事实上，这种类型的无机体系在阴离子配位和超分子化学中的潜在普遍用途尚未实现，尽管无机主体通常比有机相关物（特别是含有刘易斯酸性金属原子的那些）对阴离子提供大得多的亲和力。在建立新的合作中，该提案旨在利用英国两名主要研究人员在主族化学方面的专业知识，开发和利用盐晶格逆配位的新合成概念，其中一系列优雅的金属受体将被用作阴离子主体。一个主要领域的兴趣是合理设计的超分子主群组件使用的概念，逆协调。除了提供用于稳定不寻常的无机和有机金属阴离子的手段之外，通过基于金属的反相配体固定简单盐的阴离子提供了一种制备快离子导体的新方法。

项目成果

Diisopropylamide and TMP Turbo-Grignard Reagents: A Structural Rationale for their Contrasting Reactivities

二异丙酰胺和 TMP 涡轮格氏试剂：对比反应性的结构原理

• DOI: 10.1002/ange.201000539
• 发表时间: 2010
• 期刊: Angewandte Chemie
• 作者: Armstrong D

Direct C-H metalation with chromium(II) and iron(II): transition-metal host/benzenediide guest magnetic inverse-crown complexes.

• DOI: 10.1002/anie.200805566
• 发表时间: 2009
• 期刊: Angewandte Chemie (International ed. in English)
• 作者: Alborés P;Carrella LM;Clegg W;García-Alvarez P;Kennedy AR;Klett J;Mulvey RE;Rentschler E;Russo L
• 通讯作者: Russo L

Alkali-metal-mediated manganationII of functionalized arenes and applications of ortho-manganated products in Pd-catalyzed cross-coupling reactions with iodobenzene.

碱金属介导的功能化领域的锰和正形产物在与碘苯苯二催化的交叉偶联反应中的应用。

• DOI: 10.1002/chem.200701597
• 发表时间: 2008
• 期刊: CHEMISTRY-A EUROPEAN JOURNAL
• 影响因子: 4.3
• 作者: Blair, Victoria L.;Clegg, William;Conway, Ben;Hevia, Eva;Kennedy, Alan;Klett, Jan;Mulvey, Robert E.;Russo, Luca
• 通讯作者: Russo, Luca