Heavy atom radicals as conductive and magnetic materials

重原子自由基作为导电和磁性材料

• 批准号: 551-2008
• 负责人: Oakley, Richard
• 金额: $ 7.58万
• 依托单位: University of Waterloo
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2010
• 资助国家: 加拿大
• 起止时间: 2010-01-01 至 2011-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=449126
• 关键词: Heavy; atom; radicals; conductive; magnetic

The construction of molecules with complex structures is a central theme of chemical research. In the last two decades synthetic chemists have carried this concept of molecular design into an entirely new realm. They have focussed their attention on the ultimate structural challenge - the crystallization of discrete molecular systems with predetermined packing patterns, i.e., the control of solid state architecture at the sub-nanoscale level. The objectives of controlled crystal growth vary widely, but share a common theme, namely the need to arrange molecules so that the resulting supramolecular assembly has the desired structure, stability and property. Securing any one of these three objectives represents a challenge in its own right, but success is only truly achieved when all three goals are accomplished at the same time.

构建具有复杂结构的分子是化学研究的中心主题。在过去的二十年里，合成化学家们将分子设计的概念带入了一个全新的领域。他们将注意力集中在最终的结构挑战上-具有预定堆积模式的离散分子系统的结晶，即，在亚纳米级控制固态结构。受控晶体生长的目标变化很大，但有一个共同的主题，即需要排列分子，使得所得的超分子组装体具有所需的结构、稳定性和性质。实现这三个目标中的任何一个本身都是一项挑战，但只有同时实现所有三个目标，才能真正取得成功。