Theoretical study of block copolymer self-assembly

嵌段共聚物自组装的理论研究

• 批准号: 288213-2007
• 负责人: Wickham, Robert
• 金额: $ 1.37万
• 依托单位: University of Guelph
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2010
• 资助国家: 加拿大
• 起止时间: 2010-01-01 至 2011-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=456553
• 关键词: Theoretical; study; block; copolymer; self

Polymers are long, chain-like molecules that can occur naturally (e.g., DNA) or can be produced in the lab via synthetic techniques (e.g., polystyrene). The rubber and plastics in our everyday lives are made of polymers. Block copolymers are produced by specialized synthetic techniques that chemically bond the end of one polymer species, or block (e.g., polystyrene) to a different polymer species (e.g., polyisoprene). The tendency for unlike blocks to repel would lead the system to separate into macroscopic domains of each species, if it weren't for the chemical bond between the blocks. The best the block copolymer can do is to separate its blocks into domain structures on a scale set by the size of the polymer, that is, tens of nanometers. The ability to spontaneously organize (self-assemble) into these microstructures make these materials potentially useful in applications requiring such resolution. For example, there is an ongoing, world-wide effort to investigate the use of block copolymers as structural templates for lithography, and for the production of ordered arrays of metallic nano-dots and nano-wires. These templates hold the promise of shrinking microelectronic circuits to the 10 nm scale, below that accessible to traditional photolithography. One aspect of my research centres on understanding how confinement of a block copolymer into a cylindrical nanopore influences the self-assembly process and creates new microstructures. This may lead to potentially novel applications. When processing these materials it is also important to have a fundamental understanding of the time it takes the system to form these structures, that is, the kinetics of self-assembly. This is another research focus of my group. Key questions are: What is the relation between microstructure and dynamics? What are the kinetic pathways for, and barriers to, the formation of a given structure? How do we formulate a non-equilibrium theory to answer these questions? My group tackles these problems using a combination of sophisticated analytical methods and high-performance computing. This work is expected to result in major advances in our understanding of the dynamics of block copolymers, and will enhance Canada's overall research effort in novel, soft-materials.

聚合物是可以天然存在的长链状分子（例如，DNA）或可以通过合成技术在实验室中产生（例如，聚苯乙烯）。我们日常生活中的橡胶和塑料都是由聚合物制成的。 嵌段共聚物是通过专门的合成技术生产的，所述合成技术将一种聚合物物质或嵌段（例如，聚苯乙烯）与不同的聚合物种类（例如，聚异戊二烯）。如果没有块之间的化学键，不同块之间相互排斥的趋势将导致系统分离成每个物种的宏观区域。嵌段共聚物所能做的最好的事情是将其嵌段分离成由聚合物尺寸设定的尺度上的域结构，即数十纳米。自发组织（自组装）成这些微结构的能力使这些材料在需要这种分辨率的应用中具有潜在的用途。 例如，世界范围内正在努力研究嵌段共聚物作为光刻的结构模板的用途，以及用于生产金属纳米点和纳米线的有序阵列。这些模板有希望将微电子电路缩小到10 nm的规模，低于传统光刻法。我的研究的一个方面集中在了解嵌段共聚物限制到圆柱形纳米孔中如何影响自组装过程并创建新的微观结构。这可能导致潜在的新颖应用。在处理这些材料时，对系统形成这些结构所需的时间（即自组装的动力学）有一个基本的了解也很重要。这也是我们小组的另一个研究重点。关键问题是：微观结构和动力学之间的关系是什么？形成给定结构的动力学途径和障碍是什么？我们如何用非平衡理论来回答这些问题呢？我的团队使用复杂的分析方法和高性能计算相结合来解决这些问题。这项工作预计将导致在我们的嵌段共聚物的动力学的理解的重大进展，并将提高加拿大的整体研究工作，在新的软材料。