coordination compounds based on diimines and related ligands and their application in catalysis

二亚胺及相关配体的配位化合物及其催化应用

• 批准号: 311824-2011
• 负责人: Schaper, Frank
• 金额: $ 2.55万
• 依托单位: Université de Montréal
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2011
• 资助国家: 加拿大
• 起止时间: 2011-01-01 至 2012-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=481005
• 关键词: coordination; compounds; based; diimines; related

Catalytic reactions are of extreme importance in industrial production (70-80% of all produced chemicals/pharmaceuticals involve a catalytic step) as well as in natural systems. They are not only more energy-efficient than non-catalyzed reactions, but also allow one to control selectivity, to minimize side reactions and to follow reaction pathways not accessible without a catalyst present. Catalysis is consequently one of the main principles of sustainable ("green") chemistry. Coordination complexes have found widespread applications in this regard. Their use, in particular on an industrial scale, is, however, often limited by their costs and/or their toxicity.

催化反应在工业生产（所有生产的化学品/药品的 70-80% 涉及催化步骤）以及自然系统中极其重要。它们不仅比非催化反应更节能，而且还可以控制选择性，最大限度地减少副反应，并遵循没有催化剂时无法实现的反应路径。因此，催化是可持续（“绿色”）化学的主要原理之一。配位配合物在这方面已得到广泛应用。然而，它们的使用，特别是在工业规模上的使用，常常受到它们的成本和/或它们的毒性的限制。