Causes and effects of composition changes in the ocean

海洋成分变化的原因和影响

• 批准号: 194270-2011
• 负责人: Pawlowicz, Rich
• 金额: $ 1.6万
• 依托单位: University of British Columbia
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2013
• 资助国家: 加拿大
• 起止时间: 2013-01-01 至 2014-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=523159
• 关键词: Causes; effects; composition; changes; ocean

For more than a century the assumption that the dissolved matter in seawater has a fixed relative composition, and hence can be characterized by a single variable (the "salinity"), has dominated ALL practical aspects of oceanographic science. However, although measurements of salinity using electrical conductivity can be made routinely to a precision of +/-2 mg/kg (on the new Reference Composition Salinity Scale), the true salinities of real seawater may differ by from these estimates by up to 30 mg/kg in the open ocean, 90 mg/kg in the Baltic, and potentially much more in near-coastal areas. These errors arise due to the effects of changes in the chemical composition of seawater. These composition changes are in fact the largest source of uncertainty in estimates of the thermodynamic properties of seawater (e.g., density) when using standard equations that relate them to conductivity. Although I have proposed some techniques for estimating the necessary corrections based on fundamental physical/chemical factors, these techniques are relatively immature. This is partly due to inadequacies in our knowledge of the actual composition variations and the physical, biological, and chemical processes that control them, and partly due to uncertainties in our fundamental knowledge of the theory governing conductivity/salinity/density relationships in all natural waters.

世纪以来，海水中溶解的物质具有固定的相对组成，因此可以用单一变量（“盐度”）来表征，这一假设主导了海洋科学的所有实践方面。 然而，尽管使用电导率测量盐度的常规精度可以达到+/-2 mg/kg（在新的参考成分盐度标度上），但真实的海水的真实盐度可能与这些估计值相差30 mg/kg，波罗的海为90 mg/kg，在近海岸地区可能更大。这些误差是由于海水化学成分变化的影响而产生的。 这些组成变化实际上是海水热力学性质估计中最大的不确定性来源（例如，密度），当使用将它们与电导率相关联的标准方程时。虽然我已经提出了一些技术来估计必要的修正的基础上的基本物理/化学因素，这些技术是相对不成熟的。这部分是由于我们对实际成分变化和控制它们的物理、生物和化学过程的知识不足，部分是由于我们对所有天然沃茨中电导率/盐度/密度关系理论的基础知识不确定。